A literature survey on the surface science of water adsorption on Cu

Mika Hirsimäki

A literature survey on the surface science of water adsorption on Cu

Physics

Research output: Book/Report › Commissioned report

Abstract

The method chosen by Posiva Oy (Finland) and Svensk Kärnbränslehantering AB (Sweden) for the final disposal of spent nuclear fuel is the KBS-3 method. It entails storing spent nuclear waste underground in canisters that have a protective exterior made of copper (Cu). At present, there is controversy over the extent of corrosion of Cu in anoxic water. Recent results suggest that Cu can corrode in anoxic water to a much larger extent than what has been predicted earlier.

A wealth of information exists on water-Cu interaction. Most of it has been acquired by using surface scientific means. This report reviews the recent experimental and theoretical results obtained on water-Cu interaction mechanisms.

Original language	English
Publisher	POSIVA OY
Commissioning body	Posiva Oy
Number of pages	21
Publication status	Published - May 2021
Publication type	D4 Published development or research report or study

Publication series

Name	Posiva Working Report 2018:12
Publisher	Posiva Oy

Keywords

Copper
Oxides
Water
Corrosion
Surface Science
Nuclear fuel
Disposal

ASJC Scopus subject areas

Nuclear Energy and Engineering
Metals and Alloys
Surfaces, Coatings and Films

Cite this

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abstract = "The method chosen by Posiva Oy (Finland) and Svensk K{\"a}rnbr{\"a}nslehantering AB (Sweden) for the final disposal of spent nuclear fuel is the KBS-3 method. It entails storing spent nuclear waste underground in canisters that have a protective exterior made of copper (Cu). At present, there is controversy over the extent of corrosion of Cu in anoxic water. Recent results suggest that Cu can corrode in anoxic water to a much larger extent than what has been predicted earlier. A wealth of information exists on water-Cu interaction. Most of it has been acquired by using surface scientific means. This report reviews the recent experimental and theoretical results obtained on water-Cu interaction mechanisms. ",

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AB - The method chosen by Posiva Oy (Finland) and Svensk Kärnbränslehantering AB (Sweden) for the final disposal of spent nuclear fuel is the KBS-3 method. It entails storing spent nuclear waste underground in canisters that have a protective exterior made of copper (Cu). At present, there is controversy over the extent of corrosion of Cu in anoxic water. Recent results suggest that Cu can corrode in anoxic water to a much larger extent than what has been predicted earlier. A wealth of information exists on water-Cu interaction. Most of it has been acquired by using surface scientific means. This report reviews the recent experimental and theoretical results obtained on water-Cu interaction mechanisms.

KW - Copper

KW - Oxides

KW - Water

KW - Corrosion

KW - Surface Science

KW - Nuclear fuel

KW - Disposal

UR - https://www.posiva.fi/en/index/media/reports.html

M3 - Commissioned report

T3 - Posiva Working Report 2018:12

BT - A literature survey on the surface science of water adsorption on Cu

PB - POSIVA OY

ER -

A literature survey on the surface science of water adsorption on Cu

Abstract

Publication series

Keywords

ASJC Scopus subject areas

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