Abstract
Reduced density-matrix functional theory (RDMFT) has become an appealing alternative to density-functional theory to describe electronic properties of strongly correlated systems. Here we derive exact conditions for the suitability of RDMFT to describe the two-dimensional homogeneous electron gas, which is the base system for semiconductor quantum dots and quantum Hall devices, for example. Following the method of Cioslowski and Pernal [J. Chem. Phys. 111, 3396 (1999)] we focus on the properties of power functionals of the form f(n, n') = (nn')alpha for the scaling function in the exchange-correlation energy. We show that in order to have stable and analytic solutions, and for f to satisfy the homogeneous scaling constraint, the power is restricted to 1/4
| Original language | English |
|---|---|
| Article number | 035104 |
| Number of pages | 6 |
| Journal | Physical Review B |
| Volume | 84 |
| Issue number | 3 |
| DOIs | |
| Publication status | Published - 15 Jul 2011 |
| Publication type | A1 Journal article-refereed |
Funding
We thank Katarzyna Pernal, Klaas Giesbertz, Robert van Leeuwen, and Florian Eich for helpful comments and useful discussions. This work has been supported by the Academy of Finland.
Keywords
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