Dependence of the third order nonlinear optical susceptibility on concentration and peripheral substituent of metallophthalocyanines

Beata Derkowska; Michal Wojdyla; Waclaw Bala; Katarzyna Jaworowicz; Miroslaw Karpierz; Robert Czaplicki; Bouchta Sahraoui

doi:10.1080/15421400801925927

Dependence of the third order nonlinear optical susceptibility on concentration and peripheral substituent of metallophthalocyanines

Beata Derkowska^*
, Michal Wojdyla
, Waclaw Bala
, Katarzyna Jaworowicz
, Miroslaw Karpierz
, Robert Czaplicki
, Bouchta Sahraoui

^*Corresponding author for this work

Research output: Contribution to journal › Article › Scientific › peer-review

3 Citations (Scopus)

Abstract

Third order nonlinear optical properties of metallophthalocyanines (MPcs) were investigated using degenerate four wave mixing (DFWM) method. We also studied how the replacement of peripheral substituent around the MPcs cores correlates with nonlinear optical properties. Therefore third order nonlinear optical susceptibilities (chi(<3 >)) of MPcs with liquid crystal (MPcs-LC) were investigated. We found that the chi(<3 >) values of MPcs-LC increase in comparison with the corresponding values of MPcs. We supposed that this is caused by the increase of the charge transfer effects and change of the dipole moments of the molecule with the increase of molecules dimension.

Original language	English
Pages (from-to)	965-973
Number of pages	9
Journal	Molecular Crystals and Liquid Crystals
Volume	485
DOIs	https://doi.org/10.1080/15421400801925927
Publication status	Published - 2008
Externally published	Yes
Publication type	A1 Journal article-refereed
Event	9th International Conference on Frontiers of Polymers and Advanced Materials - Cracow, Poland Duration: 8 Jul 2007 → 12 Jul 2007

Keywords

DFWM
liquid crystal (LC)
metallophthalocyanines (MPcs)
optical nonlinearity
third order nonlinear optical susceptibility
PHTHALOCYANINE THIN-FILMS

Access to Document

10.1080/15421400801925927

Cite this

@article{c56be0abdb024e88a0dee3151b430cfc,

title = "Dependence of the third order nonlinear optical susceptibility on concentration and peripheral substituent of metallophthalocyanines",

abstract = "Third order nonlinear optical properties of metallophthalocyanines (MPcs) were investigated using degenerate four wave mixing (DFWM) method. We also studied how the replacement of peripheral substituent around the MPcs cores correlates with nonlinear optical properties. Therefore third order nonlinear optical susceptibilities (chi(<3 >)) of MPcs with liquid crystal (MPcs-LC) were investigated. We found that the chi(<3 >) values of MPcs-LC increase in comparison with the corresponding values of MPcs. We supposed that this is caused by the increase of the charge transfer effects and change of the dipole moments of the molecule with the increase of molecules dimension.",

keywords = "DFWM, liquid crystal (LC), metallophthalocyanines (MPcs), optical nonlinearity, third order nonlinear optical susceptibility, PHTHALOCYANINE THIN-FILMS",

author = "Beata Derkowska and Michal Wojdyla and Waclaw Bala and Katarzyna Jaworowicz and Miroslaw Karpierz and Robert Czaplicki and Bouchta Sahraoui",

year = "2008",

doi = "10.1080/15421400801925927",

language = "English",

volume = "485",

pages = "965--973",

journal = "Molecular Crystals and Liquid Crystals",

issn = "1542-1406",

publisher = "Taylor and Francis Ltd.",

note = "9th International Conference on Frontiers of Polymers and Advanced Materials ; Conference date: 08-07-2007 Through 12-07-2007",

}

TY - JOUR

T1 - Dependence of the third order nonlinear optical susceptibility on concentration and peripheral substituent of metallophthalocyanines

AU - Derkowska, Beata

AU - Wojdyla, Michal

AU - Bala, Waclaw

AU - Jaworowicz, Katarzyna

AU - Karpierz, Miroslaw

AU - Czaplicki, Robert

AU - Sahraoui, Bouchta

PY - 2008

Y1 - 2008

N2 - Third order nonlinear optical properties of metallophthalocyanines (MPcs) were investigated using degenerate four wave mixing (DFWM) method. We also studied how the replacement of peripheral substituent around the MPcs cores correlates with nonlinear optical properties. Therefore third order nonlinear optical susceptibilities (chi(<3 >)) of MPcs with liquid crystal (MPcs-LC) were investigated. We found that the chi(<3 >) values of MPcs-LC increase in comparison with the corresponding values of MPcs. We supposed that this is caused by the increase of the charge transfer effects and change of the dipole moments of the molecule with the increase of molecules dimension.

AB - Third order nonlinear optical properties of metallophthalocyanines (MPcs) were investigated using degenerate four wave mixing (DFWM) method. We also studied how the replacement of peripheral substituent around the MPcs cores correlates with nonlinear optical properties. Therefore third order nonlinear optical susceptibilities (chi(<3 >)) of MPcs with liquid crystal (MPcs-LC) were investigated. We found that the chi(<3 >) values of MPcs-LC increase in comparison with the corresponding values of MPcs. We supposed that this is caused by the increase of the charge transfer effects and change of the dipole moments of the molecule with the increase of molecules dimension.

KW - DFWM

KW - liquid crystal (LC)

KW - metallophthalocyanines (MPcs)

KW - optical nonlinearity

KW - third order nonlinear optical susceptibility

KW - PHTHALOCYANINE THIN-FILMS

U2 - 10.1080/15421400801925927

DO - 10.1080/15421400801925927

M3 - Article

SN - 1542-1406

VL - 485

SP - 965

EP - 973

JO - Molecular Crystals and Liquid Crystals

JF - Molecular Crystals and Liquid Crystals

T2 - 9th International Conference on Frontiers of Polymers and Advanced Materials

Y2 - 8 July 2007 through 12 July 2007

ER -

Dependence of the third order nonlinear optical susceptibility on concentration and peripheral substituent of metallophthalocyanines

Abstract

Keywords

Access to Document

Fingerprint

Cite this