Determination of the collision rate coefficient between charged iodic acid clusters and iodic acid using the appearance time method

Xu Cheng He; Siddharth Iyer; Mikko Sipilä; Arttu Ylisirniö; Maija Peltola; Jenni Kontkanen; Rima Baalbaki; Mario Simon; Andreas Kürten; Yee Jun Tham; Janne Pesonen; Lauri R. Ahonen; Stavros Amanatidis; Antonio Amorim; Andrea Baccarini; Lisa Beck; Federico Bianchi; Sophia Brilke; Dexian Chen; Randall Chiu; Joachim Curtius; Lubna Dada; Antonio Dias; Josef Dommen; Neil M. Donahue; Jonathan Duplissy; Imad El Haddad; Henning Finkenzeller; Lukas Fischer; Martin Heinritzi; Victoria Hofbauer; Juha Kangasluoma; Changhyuk Kim; Theodore K. Koenig; Jakub Kubečka; Aleksandr Kvashnin; Houssni Lamkaddam; Chuan Ping Lee; Markus Leiminger; Zijun Li; Vladimir Makhmutov; Mao Xiao; Ruby Marten; Wei Nie; Antti Onnela; Eva Partoll; Tuukka Petäjä; Vili Taneli Salo; Simone Schuchmann; Gerhard Steiner; Dominik Stolzenburg; Yuri Stozhkov; Christian Tauber; António Tomé; Olli Väisänen; Miguel Vazquez-Pufleau; Rainer Volkamer; Andrea C. Wagner; Mingyi Wang; Yonghong Wang; Daniela Wimmer; Paul M. Winkler; Douglas R. Worsnop; Yusheng Wu; Chao Yan; Qing Ye; Kari Lehtinen; Tuomo Nieminen; Hanna E. Manninen; Matti Rissanen; Siegfried Schobesberger; Katrianne Lehtipalo; Urs Baltensperger; Armin Hansel; Veli Matti Kerminen; Richard C. Flagan; Jasper Kirkby; Theo Kurtén; Markku Kulmala

doi:10.1080/02786826.2020.1839013

Determination of the collision rate coefficient between charged iodic acid clusters and iodic acid using the appearance time method

Xu Cheng He, Siddharth Iyer, Mikko Sipilä, Arttu Ylisirniö, Maija Peltola, Jenni Kontkanen, Rima Baalbaki, Mario Simon, Andreas Kürten, Yee Jun Tham, Janne Pesonen, Lauri R. Ahonen, Stavros Amanatidis, Antonio Amorim, Andrea Baccarini, Lisa Beck, Federico Bianchi, Sophia Brilke, Dexian Chen, Randall ChiuJoachim Curtius, Lubna Dada, Antonio Dias, Josef Dommen, Neil M. Donahue, Jonathan Duplissy, Imad El Haddad, Henning Finkenzeller, Lukas Fischer, Martin Heinritzi, Victoria Hofbauer, Juha Kangasluoma, Changhyuk Kim, Theodore K. Koenig, Jakub Kubečka, Aleksandr Kvashnin, Houssni Lamkaddam, Chuan Ping Lee, Markus Leiminger, Zijun Li, Vladimir Makhmutov, Mao Xiao, Ruby Marten, Wei Nie, Antti Onnela, Eva Partoll, Tuukka Petäjä, Vili Taneli Salo, Simone Schuchmann, Gerhard Steiner, Dominik Stolzenburg, Yuri Stozhkov, Christian Tauber, António Tomé, Olli Väisänen, Miguel Vazquez-Pufleau, Rainer Volkamer, Andrea C. Wagner, Mingyi Wang, Yonghong Wang, Daniela Wimmer, Paul M. Winkler, Douglas R. Worsnop, Yusheng Wu, Chao Yan, Qing Ye, Kari Lehtinen, Tuomo Nieminen, Hanna E. Manninen, Matti Rissanen, Siegfried Schobesberger, Katrianne Lehtipalo, Urs Baltensperger, Armin Hansel, Veli Matti Kerminen, Richard C. Flagan, Jasper Kirkby, Theo Kurtén, Markku Kulmala

Physics

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Abstract

Ions enhance the formation rate of atmospheric aerosol particles, which play an important role in Earth’s radiative balance. Ion-induced nucleation involves the stepwise accretion of neutral monomers onto a molecular cluster containing an ion, which helps to stabilize the cluster against evaporation. Although theoretical frameworks exist to calculate the collision rate coefficients between neutral molecules and ions, they need to be experimentally confirmed, ideally under atmospherically relevant conditions of around 1000 ion pairs cm⁻³. Here, in experiments performed under atmospheric conditions in the CERN CLOUD chamber, we have measured the collision rate coefficients between neutral iodic acid (HIO₃) monomers and charged iodic acid molecular clusters containing up to 11 iodine atoms. Three methods were analytically derived to calculate ion-polar molecule collision rate coefficients. After evaluation with a kinetic model, the 50% appearance time method is found to be the most robust. The measured collision rate coefficient, averaged over all iodine clusters, is (2.4 ± 0.8)×10⁻⁹cm³ s⁻¹, which is close to the expectation from the surface charge capture theory.

Original language	English
Pages (from-to)	231-242
Number of pages	12
Journal	Aerosol Science and Technology
Volume	55
Issue number	2
Early online date	2020
DOIs	https://doi.org/10.1080/02786826.2020.1839013
Publication status	Published - 2021
Publication type	A1 Journal article-refereed

Keywords

Jingkun Jiang

Publication forum classification

Publication forum level 1

ASJC Scopus subject areas

Environmental Chemistry
General Materials Science
Pollution

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10.1080/02786826.2020.1839013Licence: CC BY

Determination of the collision rate 2020
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Final published version, 3.66 MBLicence: CC BY

http://urn.fi/URN:NBN:fi:tuni-202012188986Licence: CC BY

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He, X. C., Iyer, S., Sipilä, M., Ylisirniö, A., Peltola, M., Kontkanen, J., Baalbaki, R., Simon, M., Kürten, A., Tham, Y. J., Pesonen, J., Ahonen, L. R., Amanatidis, S., Amorim, A., Baccarini, A., Beck, L., Bianchi, F., Brilke, S., Chen, D., ... Kulmala, M. (2021). Determination of the collision rate coefficient between charged iodic acid clusters and iodic acid using the appearance time method. Aerosol Science and Technology, 55(2), 231-242. https://doi.org/10.1080/02786826.2020.1839013

@article{f80d06d95e394116bbc85af8c62eea53,

title = "Determination of the collision rate coefficient between charged iodic acid clusters and iodic acid using the appearance time method",

abstract = "Ions enhance the formation rate of atmospheric aerosol particles, which play an important role in Earth{\textquoteright}s radiative balance. Ion-induced nucleation involves the stepwise accretion of neutral monomers onto a molecular cluster containing an ion, which helps to stabilize the cluster against evaporation. Although theoretical frameworks exist to calculate the collision rate coefficients between neutral molecules and ions, they need to be experimentally confirmed, ideally under atmospherically relevant conditions of around 1000 ion pairs cm−3. Here, in experiments performed under atmospheric conditions in the CERN CLOUD chamber, we have measured the collision rate coefficients between neutral iodic acid (HIO3) monomers and charged iodic acid molecular clusters containing up to 11 iodine atoms. Three methods were analytically derived to calculate ion-polar molecule collision rate coefficients. After evaluation with a kinetic model, the 50% appearance time method is found to be the most robust. The measured collision rate coefficient, averaged over all iodine clusters, is (2.4 ± 0.8)×10−9cm3 s−1, which is close to the expectation from the surface charge capture theory.",

keywords = "Jingkun Jiang",

author = "He, {Xu Cheng} and Siddharth Iyer and Mikko Sipil{\"a} and Arttu Ylisirni{\"o} and Maija Peltola and Jenni Kontkanen and Rima Baalbaki and Mario Simon and Andreas K{\"u}rten and Tham, {Yee Jun} and Janne Pesonen and Ahonen, {Lauri R.} and Stavros Amanatidis and Antonio Amorim and Andrea Baccarini and Lisa Beck and Federico Bianchi and Sophia Brilke and Dexian Chen and Randall Chiu and Joachim Curtius and Lubna Dada and Antonio Dias and Josef Dommen and Donahue, {Neil M.} and Jonathan Duplissy and {El Haddad}, Imad and Henning Finkenzeller and Lukas Fischer and Martin Heinritzi and Victoria Hofbauer and Juha Kangasluoma and Changhyuk Kim and Koenig, {Theodore K.} and Jakub Kube{\v c}ka and Aleksandr Kvashnin and Houssni Lamkaddam and Lee, {Chuan Ping} and Markus Leiminger and Zijun Li and Vladimir Makhmutov and Mao Xiao and Ruby Marten and Wei Nie and Antti Onnela and Eva Partoll and Tuukka Pet{\"a}j{\"a} and Salo, {Vili Taneli} and Simone Schuchmann and Gerhard Steiner and Dominik Stolzenburg and Yuri Stozhkov and Christian Tauber and Ant{\'o}nio Tom{\'e} and Olli V{\"a}is{\"a}nen and Miguel Vazquez-Pufleau and Rainer Volkamer and Wagner, {Andrea C.} and Mingyi Wang and Yonghong Wang and Daniela Wimmer and Winkler, {Paul M.} and Worsnop, {Douglas R.} and Yusheng Wu and Chao Yan and Qing Ye and Kari Lehtinen and Tuomo Nieminen and Manninen, {Hanna E.} and Matti Rissanen and Siegfried Schobesberger and Katrianne Lehtipalo and Urs Baltensperger and Armin Hansel and Kerminen, {Veli Matti} and Flagan, {Richard C.} and Jasper Kirkby and Theo Kurt{\'e}n and Markku Kulmala",

year = "2021",

doi = "10.1080/02786826.2020.1839013",

language = "English",

volume = "55",

pages = "231--242",

journal = "Aerosol Science and Technology",

issn = "0278-6826",

publisher = "Taylor and Francis Ltd.",

number = "2",

}

He, XC, Iyer, S, Sipilä, M, Ylisirniö, A, Peltola, M, Kontkanen, J, Baalbaki, R, Simon, M, Kürten, A, Tham, YJ, Pesonen, J, Ahonen, LR, Amanatidis, S, Amorim, A, Baccarini, A, Beck, L, Bianchi, F, Brilke, S, Chen, D, Chiu, R, Curtius, J, Dada, L, Dias, A, Dommen, J, Donahue, NM, Duplissy, J, El Haddad, I, Finkenzeller, H, Fischer, L, Heinritzi, M, Hofbauer, V, Kangasluoma, J, Kim, C, Koenig, TK, Kubečka, J, Kvashnin, A, Lamkaddam, H, Lee, CP, Leiminger, M, Li, Z, Makhmutov, V, Xiao, M, Marten, R, Nie, W, Onnela, A, Partoll, E, Petäjä, T, Salo, VT, Schuchmann, S, Steiner, G, Stolzenburg, D, Stozhkov, Y, Tauber, C, Tomé, A, Väisänen, O, Vazquez-Pufleau, M, Volkamer, R, Wagner, AC, Wang, M, Wang, Y, Wimmer, D, Winkler, PM, Worsnop, DR, Wu, Y, Yan, C, Ye, Q, Lehtinen, K, Nieminen, T, Manninen, HE, Rissanen, M, Schobesberger, S, Lehtipalo, K, Baltensperger, U, Hansel, A, Kerminen, VM, Flagan, RC, Kirkby, J, Kurtén, T & Kulmala, M 2021, 'Determination of the collision rate coefficient between charged iodic acid clusters and iodic acid using the appearance time method', Aerosol Science and Technology, vol. 55, no. 2, pp. 231-242. https://doi.org/10.1080/02786826.2020.1839013

TY - JOUR

T1 - Determination of the collision rate coefficient between charged iodic acid clusters and iodic acid using the appearance time method

AU - He, Xu Cheng

AU - Iyer, Siddharth

AU - Sipilä, Mikko

AU - Ylisirniö, Arttu

AU - Peltola, Maija

AU - Kontkanen, Jenni

AU - Baalbaki, Rima

AU - Simon, Mario

AU - Kürten, Andreas

AU - Tham, Yee Jun

AU - Pesonen, Janne

AU - Ahonen, Lauri R.

AU - Amanatidis, Stavros

AU - Amorim, Antonio

AU - Baccarini, Andrea

AU - Beck, Lisa

AU - Bianchi, Federico

AU - Brilke, Sophia

AU - Chen, Dexian

AU - Chiu, Randall

AU - Curtius, Joachim

AU - Dada, Lubna

AU - Dias, Antonio

AU - Dommen, Josef

AU - Donahue, Neil M.

AU - Duplissy, Jonathan

AU - El Haddad, Imad

AU - Finkenzeller, Henning

AU - Fischer, Lukas

AU - Heinritzi, Martin

AU - Hofbauer, Victoria

AU - Kangasluoma, Juha

AU - Kim, Changhyuk

AU - Koenig, Theodore K.

AU - Kubečka, Jakub

AU - Kvashnin, Aleksandr

AU - Lamkaddam, Houssni

AU - Lee, Chuan Ping

AU - Leiminger, Markus

AU - Li, Zijun

AU - Makhmutov, Vladimir

AU - Xiao, Mao

AU - Marten, Ruby

AU - Nie, Wei

AU - Onnela, Antti

AU - Partoll, Eva

AU - Petäjä, Tuukka

AU - Salo, Vili Taneli

AU - Schuchmann, Simone

AU - Steiner, Gerhard

AU - Stolzenburg, Dominik

AU - Stozhkov, Yuri

AU - Tauber, Christian

AU - Tomé, António

AU - Väisänen, Olli

AU - Vazquez-Pufleau, Miguel

AU - Volkamer, Rainer

AU - Wagner, Andrea C.

AU - Wang, Mingyi

AU - Wang, Yonghong

AU - Wimmer, Daniela

AU - Winkler, Paul M.

AU - Worsnop, Douglas R.

AU - Wu, Yusheng

AU - Yan, Chao

AU - Ye, Qing

AU - Lehtinen, Kari

AU - Nieminen, Tuomo

AU - Manninen, Hanna E.

AU - Rissanen, Matti

AU - Schobesberger, Siegfried

AU - Lehtipalo, Katrianne

AU - Baltensperger, Urs

AU - Hansel, Armin

AU - Kerminen, Veli Matti

AU - Flagan, Richard C.

AU - Kirkby, Jasper

AU - Kurtén, Theo

AU - Kulmala, Markku

PY - 2021

Y1 - 2021

N2 - Ions enhance the formation rate of atmospheric aerosol particles, which play an important role in Earth’s radiative balance. Ion-induced nucleation involves the stepwise accretion of neutral monomers onto a molecular cluster containing an ion, which helps to stabilize the cluster against evaporation. Although theoretical frameworks exist to calculate the collision rate coefficients between neutral molecules and ions, they need to be experimentally confirmed, ideally under atmospherically relevant conditions of around 1000 ion pairs cm−3. Here, in experiments performed under atmospheric conditions in the CERN CLOUD chamber, we have measured the collision rate coefficients between neutral iodic acid (HIO3) monomers and charged iodic acid molecular clusters containing up to 11 iodine atoms. Three methods were analytically derived to calculate ion-polar molecule collision rate coefficients. After evaluation with a kinetic model, the 50% appearance time method is found to be the most robust. The measured collision rate coefficient, averaged over all iodine clusters, is (2.4 ± 0.8)×10−9cm3 s−1, which is close to the expectation from the surface charge capture theory.

AB - Ions enhance the formation rate of atmospheric aerosol particles, which play an important role in Earth’s radiative balance. Ion-induced nucleation involves the stepwise accretion of neutral monomers onto a molecular cluster containing an ion, which helps to stabilize the cluster against evaporation. Although theoretical frameworks exist to calculate the collision rate coefficients between neutral molecules and ions, they need to be experimentally confirmed, ideally under atmospherically relevant conditions of around 1000 ion pairs cm−3. Here, in experiments performed under atmospheric conditions in the CERN CLOUD chamber, we have measured the collision rate coefficients between neutral iodic acid (HIO3) monomers and charged iodic acid molecular clusters containing up to 11 iodine atoms. Three methods were analytically derived to calculate ion-polar molecule collision rate coefficients. After evaluation with a kinetic model, the 50% appearance time method is found to be the most robust. The measured collision rate coefficient, averaged over all iodine clusters, is (2.4 ± 0.8)×10−9cm3 s−1, which is close to the expectation from the surface charge capture theory.

KW - Jingkun Jiang

U2 - 10.1080/02786826.2020.1839013

DO - 10.1080/02786826.2020.1839013

M3 - Article

AN - SCOPUS:85096125993

SN - 0278-6826

VL - 55

SP - 231

EP - 242

JO - Aerosol Science and Technology

JF - Aerosol Science and Technology

IS - 2

ER -

Determination of the collision rate coefficient between charged iodic acid clusters and iodic acid using the appearance time method

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