Exceptional Microscale Plasticity in Amorphous Aluminum Oxide at Room Temperature

Erkka J. Frankberg, Aloshious Lambai, Jiahui Zhang, Janne Kalikka, Sergei Khakalo, Boris Paladino, Mattia Cabrioli, Nidhin G. Mathews, Turkka Salminen, Mikko Hokka, Jaakko Akola, Antti Kuronen, Erkki Levänen, Fabio Di Fonzo, Gaurav Mohanty

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Oxide glasses are an elementary group of materials in modern society, but brittleness limits their wider usability at room temperature. As an exception to the rule, amorphous aluminum oxide (a-Al2O3) is a rare diatomic glassy material exhibiting significant nanoscale plasticity at room temperature. Here, it is shown experimentally that the room temperature plasticity of a-Al2O3 extends to the microscale and high strain rates using in situ micropillar compression. All tested a-Al2O3 micropillars deform without fracture at up to 50% strain via a combined mechanism of viscous creep and shear band slip propagation. Large-scale molecular dynamics simulations align with the main experimental observations and verify the plasticity mechanism at the atomic scale. The experimental strain rates reach magnitudes typical for impact loading scenarios, such as hammer forging, with strain rates up to the order of 1 000 s−1, and the total a-Al2O3 sample volume exhibiting significant low-temperature plasticity without fracture is expanded by 5 orders of magnitude from previous observations. The discovery is consistent with the theoretical prediction that the plasticity observed in a-Al2O3 can extend to macroscopic bulk scale and suggests that amorphous oxides show significant potential to be used as light, high-strength, and damage-tolerant engineering materials.

Original languageEnglish
JournalAdvanced Materials
Publication statusE-pub ahead of print - 2023
Publication typeA1 Journal article-refereed


  • finite element modelling
  • glasses
  • micropillar compression
  • molecular dynamics simulations
  • oxides
  • plasticity
  • pulsed laser deposition

Publication forum classification

  • Publication forum level 3

ASJC Scopus subject areas

  • General Materials Science
  • Mechanics of Materials
  • Mechanical Engineering


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