Impact of Al2O3, TiO2 and ZnO addition on the crystallization of Yb3+ doped phosphate glass-ceramic

Mikko Hongisto; Otto Linros; Sylvain Danto; Veronique Jubera; Laeticia Petit

doi:10.1016/j.materresbull.2022.112032

Impact of Al₂O₃, TiO₂ and ZnO addition on the crystallization of Yb³⁺ doped phosphate glass-ceramic

Mikko Hongisto, Otto Linros, Sylvain Danto, Veronique Jubera, Laeticia Petit

Physics

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Abstract

New Yb³⁺-doped phosphate glasses with a composition of (98.75-x) (90 NaPO₃ – 10 Na₂O) – x (Al₂O₃, TiO₂, or ZnO) – 1.25 Yb₂O₃ (in mol-%), with x from 0 to 3, were prepared via conventional melting and quenching process. The thermal and physical properties were studied by differential thermal analysis (DTA) and density measurement, respectively. The glass structure was investigated using visible/infrared spectroscopy and the crystallization properties of the glasses using XRD. Changes in the glass composition were found to have an impact on the glass structure and more importantly on the crystallization process; the addition of Al₂O₃, TiO₂ and ZnO promotes the precipitation of the Na₅P₃O₁₀ crystalline phase at the expense of NaYb(P₂O₇) and NaPO₃ phases and more importantly, promotes surface crystallization at the expense of bulk crystallization.

Original language	English
Article number	112032
Number of pages	9
Journal	Materials Research Bulletin
Volume	157
Early online date	13 Sept 2022
DOIs	https://doi.org/10.1016/j.materresbull.2022.112032
Publication status	Published - Jan 2023
Publication type	A1 Journal article-refereed

Publication forum classification

Publication forum level 1

ASJC Scopus subject areas

Materials Science(all)
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering

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10.1016/j.materresbull.2022.112032Licence: CC BY

1-s2.0-S0025540822003038-mainFinal published version, 2.61 MBLicence: CC BY

https://urn.fi/URN:NBN:fi:tuni-202210047410Licence: CC BY

Cite this

@article{8db5ec903f76468ab7ea4cebcd82af96,

title = "Impact of Al2O3, TiO2 and ZnO addition on the crystallization of Yb3+ doped phosphate glass-ceramic",

abstract = "New Yb3+-doped phosphate glasses with a composition of (98.75-x) (90 NaPO3 – 10 Na2O) – x (Al2O3, TiO2, or ZnO) – 1.25 Yb2O3 (in mol-%), with x from 0 to 3, were prepared via conventional melting and quenching process. The thermal and physical properties were studied by differential thermal analysis (DTA) and density measurement, respectively. The glass structure was investigated using visible/infrared spectroscopy and the crystallization properties of the glasses using XRD. Changes in the glass composition were found to have an impact on the glass structure and more importantly on the crystallization process; the addition of Al2O3, TiO2 and ZnO promotes the precipitation of the Na5P3O10 crystalline phase at the expense of NaYb(P2O7) and NaPO3 phases and more importantly, promotes surface crystallization at the expense of bulk crystallization.",

author = "Mikko Hongisto and Otto Linros and Sylvain Danto and Veronique Jubera and Laeticia Petit",

note = "Funding Information: Academy of Finland Flagship Programme of Photonics Research and Innovation and Academy Project [grant numbers PREIN-320,165, 326,418]; French Region Nouvelle-Aquitaine [grant number 2019–1R1MO1]; LIGHT S&T Graduate Program in PIA3 Investment for the Future Program [grant number ANR-17-EURE-0027]. Funding Information: This work made use of Tampere Microscopy Center facilities at Tampere University. Publisher Copyright: {\textcopyright} 2022",

year = "2023",

month = jan,

doi = "10.1016/j.materresbull.2022.112032",

language = "English",

volume = "157",

journal = "Materials Research Bulletin",

issn = "0025-5408",

publisher = "Elsevier",

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TY - JOUR

T1 - Impact of Al2O3, TiO2 and ZnO addition on the crystallization of Yb3+ doped phosphate glass-ceramic

AU - Hongisto, Mikko

AU - Linros, Otto

AU - Danto, Sylvain

AU - Jubera, Veronique

AU - Petit, Laeticia

N1 - Funding Information: Academy of Finland Flagship Programme of Photonics Research and Innovation and Academy Project [grant numbers PREIN-320,165, 326,418]; French Region Nouvelle-Aquitaine [grant number 2019–1R1MO1]; LIGHT S&T Graduate Program in PIA3 Investment for the Future Program [grant number ANR-17-EURE-0027]. Funding Information: This work made use of Tampere Microscopy Center facilities at Tampere University. Publisher Copyright: © 2022

PY - 2023/1

Y1 - 2023/1

N2 - New Yb3+-doped phosphate glasses with a composition of (98.75-x) (90 NaPO3 – 10 Na2O) – x (Al2O3, TiO2, or ZnO) – 1.25 Yb2O3 (in mol-%), with x from 0 to 3, were prepared via conventional melting and quenching process. The thermal and physical properties were studied by differential thermal analysis (DTA) and density measurement, respectively. The glass structure was investigated using visible/infrared spectroscopy and the crystallization properties of the glasses using XRD. Changes in the glass composition were found to have an impact on the glass structure and more importantly on the crystallization process; the addition of Al2O3, TiO2 and ZnO promotes the precipitation of the Na5P3O10 crystalline phase at the expense of NaYb(P2O7) and NaPO3 phases and more importantly, promotes surface crystallization at the expense of bulk crystallization.

AB - New Yb3+-doped phosphate glasses with a composition of (98.75-x) (90 NaPO3 – 10 Na2O) – x (Al2O3, TiO2, or ZnO) – 1.25 Yb2O3 (in mol-%), with x from 0 to 3, were prepared via conventional melting and quenching process. The thermal and physical properties were studied by differential thermal analysis (DTA) and density measurement, respectively. The glass structure was investigated using visible/infrared spectroscopy and the crystallization properties of the glasses using XRD. Changes in the glass composition were found to have an impact on the glass structure and more importantly on the crystallization process; the addition of Al2O3, TiO2 and ZnO promotes the precipitation of the Na5P3O10 crystalline phase at the expense of NaYb(P2O7) and NaPO3 phases and more importantly, promotes surface crystallization at the expense of bulk crystallization.

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DO - 10.1016/j.materresbull.2022.112032

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