Abstract
Dirhodium(II) catalysts have been widely used as a remarkable tool in organic synthesis, ultimately resulting in a myriad of transformations and formation of a wide variety of compounds, every so often intermediaries in drug synthesis. Aiming at a more sustainable chemistry, several methods suitable for the reutilisation of expensive dirhodium complexes have been developed. Herein, we provide a combined overview of the available methods for recovering and reusing dirhodium(II) metal complexes in catalysis, covering homogeneous catalysis as well as heterogenisation methods.
Original language | English |
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Pages (from-to) | 3357-3378 |
Number of pages | 22 |
Journal | Organic and Biomolecular Chemistry |
Volume | 10 |
Issue number | 17 |
DOIs | |
Publication status | Published - 2012 |
Publication type | A1 Journal article-refereed |
Funding
We would like to thank the financial support provided by Fundacao para a Ciencia e Tecnologia and FEDER (PTDC/QUI-QUI/099389/2008, PTDC/QUI/70902/2006, SFRH/BPD/46589/2008, PEst-OE/SAU/UI4013/2011) that has allowed us to study and develop new methodologies in dirhodium-catalysed transformations over the years.
Keywords
- C-H INSERTION
- ACTIVE PHARMACEUTICAL INGREDIENTS
- ALPHA-DIAZOCARBONYL COMPOUNDS
- CHIRAL LEWIS-ACID
- CYCLOPROPANATION REACTIONS
- ASYMMETRIC-SYNTHESIS
- RHODIUM CARBENOIDS
- IONIC LIQUID
- HOMOGENEOUS CATALYSIS
- SUPERCRITICAL FLUIDS