Model kinetics of Surface Relief Gratings formation in organic thin films: Experimental and Monte Carlo studies

G. Pawlik, W. Kordas, A. C. Mitus, B. Sahraoui, R. Czaplicki, F. Kajzar

Research output: Chapter in Book/Report/Conference proceedingConference contributionScientificpeer-review

5 Citations (Scopus)

Abstract

The semi-macroscopic mechanisms responsible for the surface relief gratings (SRG) formation on azobenzene-containing films are far from deep understanding.(1) We present the results of experimental studies of SRG in PMMA and PVK polymeric matrices. The Monte Carlo (MC) kinetics of polymeric movements is reported for recently proposed model 2 which mimics the effect of mass transport along the direction of light modulation, resulting from multiple trans cis photoisomerisation cycles of functionalized dyes. We show that the model, symmetric on "microscopic" level, leads to a directed mass transfer from bright to dark places. Preliminary studies show that the centers of mass of polymer chains undergo a normal diffusion under the light illumination. No global light-induced ordering of polymeric chains was detected. MC studies were performed for a system consisting of half a million of model monomers.

Original languageEnglish
Title of host publicationOptical Materials In Defence Systems Technology IV
EditorsJG Grote, F Kajzar, M Lindgren
Place of PublicationBELLINGHAM
PublisherSPIE
Pages74007-74007
Number of pages7
ISBN (Print)978-0-8194-6898-7
DOIs
Publication statusPublished - 2007
Externally publishedYes
Publication typeA4 Article in conference proceedings
EventConference on Optical Materials in Defence Systems Technology IV - Florence, Italy
Duration: 17 Sept 200718 Sept 2007

Publication series

NamePROCEEDINGS OF THE SOCIETY OF PHOTO-OPTICAL INSTRUMENTATION ENGINEERS (SPIE)
PublisherSPIE-INT SOC OPTICAL ENGINEERING
Volume6740
ISSN (Print)0277-786X

Conference

ConferenceConference on Optical Materials in Defence Systems Technology IV
Country/TerritoryItaly
Period17/09/0718/09/07

Keywords

  • surface relief grating
  • Monte Carlo
  • two wave mixing
  • AZO POLYMER-FILMS
  • DIFFRACTION GRATINGS
  • DIFFUSION

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