Multifunctional Porous Poly(vinylidene fluoride)-graft-Poly(butyl methacrylate) with Good Li+ Ion Conductivity

Sanjoy Samanta; Dhruba P. Chatterjee; Rama K. Layek; Arun K. Nandi

doi:10.1002/macp.201000472

Multifunctional Porous Poly(vinylidene fluoride)-graft-Poly(butyl methacrylate) with Good Li+ Ion Conductivity

Sanjoy Samanta, Dhruba P. Chatterjee, Rama K. Layek, Arun K. Nandi

Research output: Contribution to journal › Article › Scientific › peer-review

38 Citations (Scopus)

Abstract

PnBMA is grafted on PVDF using ATRP in NMP solution at 90 degrees C and characterized by means of 1D and 2D NMR. F-19 NMR spectra clearly reveal that the attack occurs on the head-head >CF2 groups. Cast PB films show a honeycomb-patterned porous microstructure, and the "breath-figure" model is used to explain pore formation. FT-IR spectra suggest a supramolecular interaction between >C=O groups of PnBMA and >CF2 groups of PVDF. Storage modulus, loss modulus and stress at break decrease with graft conversion, but the strain at break increases significantly. The toughness of the copolymers also increases dramatically (882%). The porous materials can be applied as solid-state electrolytes (Li+-doped) with good ionic conductivity (10(-5) S.cm(-1)).

Original language	English
Pages (from-to)	134-149
Number of pages	16
Journal	Macromolecular Chemistry and Physics
Volume	212
Issue number	2
DOIs	https://doi.org/10.1002/macp.201000472
Publication status	Published - 18 Jan 2011
Publication type	A1 Journal article-refereed

Keywords

ATRP
graft copolymers
Li+ ion conductivity
mechanical properties
porous morphology
TRANSFER RADICAL POLYMERIZATION
GRAFT COPOLYMER
BREATH FIGURE
SURFACE MODIFICATION
POLYSTYRENE FILMS
CHAIN STRUCTURE
FLUORIDE)
MEMBRANES
POLYMERS
ELECTROLYTES

Access to Document

10.1002/macp.201000472

Cite this

@article{81fe12fcba014d56a54350b7c6202312,

title = "Multifunctional Porous Poly(vinylidene fluoride)-graft-Poly(butyl methacrylate) with Good Li+ Ion Conductivity",

abstract = "PnBMA is grafted on PVDF using ATRP in NMP solution at 90 degrees C and characterized by means of 1D and 2D NMR. F-19 NMR spectra clearly reveal that the attack occurs on the head-head >CF2 groups. Cast PB films show a honeycomb-patterned porous microstructure, and the {"}breath-figure{"} model is used to explain pore formation. FT-IR spectra suggest a supramolecular interaction between >C=O groups of PnBMA and >CF2 groups of PVDF. Storage modulus, loss modulus and stress at break decrease with graft conversion, but the strain at break increases significantly. The toughness of the copolymers also increases dramatically (882%). The porous materials can be applied as solid-state electrolytes (Li+-doped) with good ionic conductivity (10(-5) S.cm(-1)).",

keywords = "ATRP, graft copolymers, Li+ ion conductivity, mechanical properties, porous morphology, TRANSFER RADICAL POLYMERIZATION, GRAFT COPOLYMER, BREATH FIGURE, SURFACE MODIFICATION, POLYSTYRENE FILMS, CHAIN STRUCTURE, FLUORIDE), MEMBRANES, POLYMERS, ELECTROLYTES",

author = "Sanjoy Samanta and Chatterjee, {Dhruba P.} and Layek, {Rama K.} and Nandi, {Arun K.}",

year = "2011",

month = jan,

day = "18",

doi = "10.1002/macp.201000472",

language = "English",

volume = "212",

pages = "134--149",

journal = "Macromolecular Chemistry and Physics",

issn = "1022-1352",

publisher = "Wiley-VCH Verlag",

number = "2",

}

TY - JOUR

T1 - Multifunctional Porous Poly(vinylidene fluoride)-graft-Poly(butyl methacrylate) with Good Li+ Ion Conductivity

AU - Samanta, Sanjoy

AU - Chatterjee, Dhruba P.

AU - Layek, Rama K.

AU - Nandi, Arun K.

PY - 2011/1/18

Y1 - 2011/1/18

N2 - PnBMA is grafted on PVDF using ATRP in NMP solution at 90 degrees C and characterized by means of 1D and 2D NMR. F-19 NMR spectra clearly reveal that the attack occurs on the head-head >CF2 groups. Cast PB films show a honeycomb-patterned porous microstructure, and the "breath-figure" model is used to explain pore formation. FT-IR spectra suggest a supramolecular interaction between >C=O groups of PnBMA and >CF2 groups of PVDF. Storage modulus, loss modulus and stress at break decrease with graft conversion, but the strain at break increases significantly. The toughness of the copolymers also increases dramatically (882%). The porous materials can be applied as solid-state electrolytes (Li+-doped) with good ionic conductivity (10(-5) S.cm(-1)).

AB - PnBMA is grafted on PVDF using ATRP in NMP solution at 90 degrees C and characterized by means of 1D and 2D NMR. F-19 NMR spectra clearly reveal that the attack occurs on the head-head >CF2 groups. Cast PB films show a honeycomb-patterned porous microstructure, and the "breath-figure" model is used to explain pore formation. FT-IR spectra suggest a supramolecular interaction between >C=O groups of PnBMA and >CF2 groups of PVDF. Storage modulus, loss modulus and stress at break decrease with graft conversion, but the strain at break increases significantly. The toughness of the copolymers also increases dramatically (882%). The porous materials can be applied as solid-state electrolytes (Li+-doped) with good ionic conductivity (10(-5) S.cm(-1)).

KW - ATRP

KW - graft copolymers

KW - Li+ ion conductivity

KW - mechanical properties

KW - porous morphology

KW - TRANSFER RADICAL POLYMERIZATION

KW - GRAFT COPOLYMER

KW - BREATH FIGURE

KW - SURFACE MODIFICATION

KW - POLYSTYRENE FILMS

KW - CHAIN STRUCTURE

KW - FLUORIDE)

KW - MEMBRANES

KW - POLYMERS

KW - ELECTROLYTES

U2 - 10.1002/macp.201000472

DO - 10.1002/macp.201000472

M3 - Article

SN - 1022-1352

VL - 212

SP - 134

EP - 149

JO - Macromolecular Chemistry and Physics

JF - Macromolecular Chemistry and Physics

IS - 2

ER -

Multifunctional Porous Poly(vinylidene fluoride)-graft-Poly(butyl methacrylate) with Good Li+ Ion Conductivity

Abstract

Keywords

Access to Document

Fingerprint

Cite this