Photoinduced surface patterning of azobenzene-containing supramolecular dendrons, dendrimers and dendronized polymers

  • Jaana Vapaavuori
  • , Arri Priimagi*
  • , Antti J. Soininen
  • , Nadia Canilho
  • , Edis Kasëmi
  • , Janne Ruokolainen
  • , Matti Kaivola
  • , Olli Ikkala
  • *Corresponding author for this work

    Research output: Contribution to journalArticleScientificpeer-review

    12 Citations (Scopus)

    Abstract

    Ionic complexes of azobenzenes and dendritic structures are shown to exhibit efficient light-induced mass transport upon irradiation with a light interference pattern. Surface-relief gratings (SRGs) with modulation depths of up to 550 nm were successfully inscribed. We compare the SRG formation in three generations of supramolecular dendrons, dendrimers, and dendronized polymers and demonstrate that the grating formation process is destructed by the existence of self-assembled structures as well as by overly large size of the dendronic complexes.

    Original languageEnglish
    Pages (from-to)711-722
    Number of pages12
    JournalOptical Materials Express
    Volume3
    Issue number6
    DOIs
    Publication statusPublished - 2013
    Publication typeA1 Journal article-refereed

    ASJC Scopus subject areas

    • Electronic, Optical and Magnetic Materials

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