Preparation of zinc oxide free, transparent rubber nanocomposites using a layered double hydroxide filler

Amit Das; De Yi Wang; Andreas Leuteritz; Kalaivani Subramaniam; H. Chris Greenwell; Udo Wagenknecht; Gert Heinrich

doi:10.1039/c0jm03784b

Preparation of zinc oxide free, transparent rubber nanocomposites using a layered double hydroxide filler

Amit Das
, De Yi Wang^*
, Andreas Leuteritz
, Kalaivani Subramaniam
, H. Chris Greenwell
, Udo Wagenknecht
, Gert Heinrich

^*Corresponding author for this work

Research output: Contribution to journal › Article › Scientific › peer-review

102 Citations (Scopus)

Abstract

A layered double hydroxide (LDH) mineral filler particle has been designed and employed in rubber vulcanization to prepare a more environmentally friendly rubber composite. The LDH delivers zinc ions in the vulcanization process as accelerators, stearate anions as activators and simultaneously the mineral sheets act as a nanofiller to reinforce the rubber matrix whilst totally replacing the separate zinc oxide (ZnO) and stearic acid conventionally used in the formulation of rubber. This method leads to a significant reduction (nearly 10 times) of the zinc level and yields excellent transparent properties in the final rubber product. The morphological characterization, rheometric curing behaviour, mechanical properties and uniaxial multi-hysteresis behaviours of the resultant rubber/LDH nanocomposite are studied in this paper.

Original language	English
Pages (from-to)	7194-7200
Number of pages	7
Journal	Journal of Materials Chemistry
Volume	21
Issue number	20
DOIs	https://doi.org/10.1039/c0jm03784b
Publication status	Published - 28 May 2011
Publication type	A1 Journal article-refereed

ASJC Scopus subject areas

General Chemistry
Materials Chemistry

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abstract = "A layered double hydroxide (LDH) mineral filler particle has been designed and employed in rubber vulcanization to prepare a more environmentally friendly rubber composite. The LDH delivers zinc ions in the vulcanization process as accelerators, stearate anions as activators and simultaneously the mineral sheets act as a nanofiller to reinforce the rubber matrix whilst totally replacing the separate zinc oxide (ZnO) and stearic acid conventionally used in the formulation of rubber. This method leads to a significant reduction (nearly 10 times) of the zinc level and yields excellent transparent properties in the final rubber product. The morphological characterization, rheometric curing behaviour, mechanical properties and uniaxial multi-hysteresis behaviours of the resultant rubber/LDH nanocomposite are studied in this paper.",

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AU - Das, Amit

AU - Wang, De Yi

AU - Leuteritz, Andreas

AU - Subramaniam, Kalaivani

AU - Greenwell, H. Chris

AU - Wagenknecht, Udo

AU - Heinrich, Gert

PY - 2011/5/28

Y1 - 2011/5/28

N2 - A layered double hydroxide (LDH) mineral filler particle has been designed and employed in rubber vulcanization to prepare a more environmentally friendly rubber composite. The LDH delivers zinc ions in the vulcanization process as accelerators, stearate anions as activators and simultaneously the mineral sheets act as a nanofiller to reinforce the rubber matrix whilst totally replacing the separate zinc oxide (ZnO) and stearic acid conventionally used in the formulation of rubber. This method leads to a significant reduction (nearly 10 times) of the zinc level and yields excellent transparent properties in the final rubber product. The morphological characterization, rheometric curing behaviour, mechanical properties and uniaxial multi-hysteresis behaviours of the resultant rubber/LDH nanocomposite are studied in this paper.

AB - A layered double hydroxide (LDH) mineral filler particle has been designed and employed in rubber vulcanization to prepare a more environmentally friendly rubber composite. The LDH delivers zinc ions in the vulcanization process as accelerators, stearate anions as activators and simultaneously the mineral sheets act as a nanofiller to reinforce the rubber matrix whilst totally replacing the separate zinc oxide (ZnO) and stearic acid conventionally used in the formulation of rubber. This method leads to a significant reduction (nearly 10 times) of the zinc level and yields excellent transparent properties in the final rubber product. The morphological characterization, rheometric curing behaviour, mechanical properties and uniaxial multi-hysteresis behaviours of the resultant rubber/LDH nanocomposite are studied in this paper.

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DO - 10.1039/c0jm03784b

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ER -

Preparation of zinc oxide free, transparent rubber nanocomposites using a layered double hydroxide filler

Abstract

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