Rh(II) catalysed intramolecular C-H insertion of diazo substrates in water: a simple and efficient approach to catalyst reuse

NR Candeias; PMP Gois; CAM Afonso

doi:10.1039/b414233k

Rh(II) catalysed intramolecular C-H insertion of diazo substrates in water: a simple and efficient approach to catalyst reuse

NR Candeias
, PMP Gois
, CAM Afonso

Research output: Contribution to journal › Article › Scientific › peer-review

55 Citations (Scopus)

20 Downloads (Pure)

Abstract

Water is an efficient solvent for the Rh-2(OAc)(4) catalysed intramolecular C - H insertion of a range of diazo substrates without competitive water insertion. Due to the high solubility and stability of the catalyst in water, the catalyst can be efficiently reused.

Original language	English
Pages (from-to)	391-393
Number of pages	3
Journal	Chemical Communications
Issue number	3
DOIs	https://doi.org/10.1039/b414233k
Publication status	Published - 2005
Externally published	Yes
Publication type	A1 Journal article-refereed

Keywords

DIAZOACETAMIDES
DIAZOCARBONYL
STEREOCONTROL
CARBENOIDS
ACTIVATION
LACTAMS

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10.1039/b414233k

3. Chem Commun, 2005, 391Final published version, 246 KB

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title = "Rh(II) catalysed intramolecular C-H insertion of diazo substrates in water: a simple and efficient approach to catalyst reuse",

abstract = "Water is an efficient solvent for the Rh-2(OAc)(4) catalysed intramolecular C - H insertion of a range of diazo substrates without competitive water insertion. Due to the high solubility and stability of the catalyst in water, the catalyst can be efficiently reused.",

keywords = "DIAZOACETAMIDES, DIAZOCARBONYL, STEREOCONTROL, CARBENOIDS, ACTIVATION, LACTAMS",

author = "NR Candeias and PMP Gois and CAM Afonso",

year = "2005",

doi = "10.1039/b414233k",

language = "English",

pages = "391--393",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "3",

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T1 - Rh(II) catalysed intramolecular C-H insertion of diazo substrates in water: a simple and efficient approach to catalyst reuse

AU - Candeias, NR

AU - Gois, PMP

AU - Afonso, CAM

PY - 2005

Y1 - 2005

N2 - Water is an efficient solvent for the Rh-2(OAc)(4) catalysed intramolecular C - H insertion of a range of diazo substrates without competitive water insertion. Due to the high solubility and stability of the catalyst in water, the catalyst can be efficiently reused.

AB - Water is an efficient solvent for the Rh-2(OAc)(4) catalysed intramolecular C - H insertion of a range of diazo substrates without competitive water insertion. Due to the high solubility and stability of the catalyst in water, the catalyst can be efficiently reused.

KW - DIAZOACETAMIDES

KW - DIAZOCARBONYL

KW - STEREOCONTROL

KW - CARBENOIDS

KW - ACTIVATION

KW - LACTAMS

U2 - 10.1039/b414233k

DO - 10.1039/b414233k

M3 - Article

SN - 1359-7345

SP - 391

EP - 393

JO - Chemical Communications

JF - Chemical Communications

IS - 3

ER -

Rh(II) catalysed intramolecular C-H insertion of diazo substrates in water: a simple and efficient approach to catalyst reuse

Abstract

Keywords

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