Role of iodine oxoacids in atmospheric aerosol nucleation

Xu-Cheng He; Yee Jun Tham; Lubna Dada; Mingyi Wang; Henning Finkenzeller; Dominik Stolzenburg; Siddharth Iyer; Mario Simon; Andreas Kürten; Jiali Shen; Birte Rörup; Matti Rissanen; Siegfried Schobesberger; Rima Baalbaki; Dongyu S. Wang; Theodore K. Koenig; Tuija Jokinen; Nina Sarnela; Lisa J. Beck; João Almeida; Stavros Amanatidis; António Amorim; Farnoush Ataei; Andrea Baccarini; Barbara Bertozzi; Federico Bianchi; Sophia Brilke; Lucía Caudillo; Dexian Chen; Randall Chiu; Biwu Chu; António Dias; Aijun Ding; Josef Dommen; Jonathan Duplissy; Imad El Haddad; Loïc Gonzalez Carracedo; Manuel Granzin; Armin Hansel; Martin Heinritzi; Victoria Hofbauer; Heikki Junninen; Juha Kangasluoma; Deniz Kemppainen; Changhyuk Kim; Weimeng Kong; Jordan E. Krechmer; Aleksander Kvashin; Totti Laitinen; Houssni Lamkaddam; Chuan Ping Lee; Katrianne Lehtipalo; Markus Leiminger; Zijun Li; Vladimir Makhmutov; Hanna E. Manninen; Guillaume Marie; Ruby Marten; Serge Mathot; Roy L. Mauldin; Bernhard Mentler; Ottmar Möhler; Tatjana Müller; Wei Nie; Antti Onnela; Tuukka Petäjä; Joschka Pfeifer; Maxim Philippov; Ananth Ranjithkumar; Alfonso Saiz-Lopez; Imre Salma; Wiebke Scholz; Simone Schuchmann; Benjamin Schulze; Gerhard Steiner; Yuri Stozhkov; Christian Tauber; António Tomé; Roseline C. Thakur; Olli Väisänen; Miguel Vazquez-Pufleau; Andrea C. Wagner; Yonghong Wang; Stefan K. Weber; Paul M. Winkler; Yusheng Wu; Mao Xiao; Chao Yan; Qing Ye; Arttu Ylisirniö; Marcel Zauner-Wieczorek; Qiaozhi Zha; Putian Zhou; Richard C. Flagan; Joachim Curtius; Urs Baltensperger; Markku Kulmala; Veli-Matti Kerminen; Theo Kurtén; Neil M. Donahue; Rainer Volkamer; Jasper Kirkby; Douglas R. Worsnop; Mikko Sipilä

doi:10.1126/science.abe0298

Role of iodine oxoacids in atmospheric aerosol nucleation

Xu-Cheng He, Yee Jun Tham, Lubna Dada, Mingyi Wang, Henning Finkenzeller, Dominik Stolzenburg, Siddharth Iyer, Mario Simon, Andreas Kürten, Jiali Shen, Birte Rörup, Matti Rissanen, Siegfried Schobesberger, Rima Baalbaki, Dongyu S. Wang, Theodore K. Koenig, Tuija Jokinen, Nina Sarnela, Lisa J. Beck, João AlmeidaStavros Amanatidis, António Amorim, Farnoush Ataei, Andrea Baccarini, Barbara Bertozzi, Federico Bianchi, Sophia Brilke, Lucía Caudillo, Dexian Chen, Randall Chiu, Biwu Chu, António Dias, Aijun Ding, Josef Dommen, Jonathan Duplissy, Imad El Haddad, Loïc Gonzalez Carracedo, Manuel Granzin, Armin Hansel, Martin Heinritzi, Victoria Hofbauer, Heikki Junninen, Juha Kangasluoma, Deniz Kemppainen, Changhyuk Kim, Weimeng Kong, Jordan E. Krechmer, Aleksander Kvashin, Totti Laitinen, Houssni Lamkaddam, Chuan Ping Lee, Katrianne Lehtipalo, Markus Leiminger, Zijun Li, Vladimir Makhmutov, Hanna E. Manninen, Guillaume Marie, Ruby Marten, Serge Mathot, Roy L. Mauldin, Bernhard Mentler, Ottmar Möhler, Tatjana Müller, Wei Nie, Antti Onnela, Tuukka Petäjä, Joschka Pfeifer, Maxim Philippov, Ananth Ranjithkumar, Alfonso Saiz-Lopez, Imre Salma, Wiebke Scholz, Simone Schuchmann, Benjamin Schulze, Gerhard Steiner, Yuri Stozhkov, Christian Tauber, António Tomé, Roseline C. Thakur, Olli Väisänen, Miguel Vazquez-Pufleau, Andrea C. Wagner, Yonghong Wang, Stefan K. Weber, Paul M. Winkler, Yusheng Wu, Mao Xiao, Chao Yan, Qing Ye, Arttu Ylisirniö, Marcel Zauner-Wieczorek, Qiaozhi Zha, Putian Zhou, Richard C. Flagan, Joachim Curtius, Urs Baltensperger, Markku Kulmala, Veli-Matti Kerminen, Theo Kurtén, Neil M. Donahue, Rainer Volkamer, Jasper Kirkby, Douglas R. Worsnop, Mikko Sipilä

Physics

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Abstract

Iodic acid (HIO3) is known to form aerosol particles in coastal marine regions, but predicted nucleation and growth rates are lacking. Using the CERN CLOUD (Cosmics Leaving Outdoor Droplets) chamber, we find that the nucleation rates of HIO3 particles are rapid, even exceeding sulfuric acid–ammonia rates under similar conditions. We also find that ion-induced nucleation involves IO3− and the sequential addition of HIO3 and that it proceeds at the kinetic limit below +10°C. In contrast, neutral nucleation involves the repeated sequential addition of iodous acid (HIO2) followed by HIO3, showing that HIO2 plays a key stabilizing role. Freshly formed particles are composed almost entirely of HIO3, which drives rapid particle growth at the kinetic limit. Our measurements indicate that iodine oxoacid particle formation can compete with sulfuric acid in pristine regions of the atmosphere.

Original language	English
Pages (from-to)	589-595
Number of pages	8
Journal	Science
Volume	371
Issue number	6529
DOIs	https://doi.org/10.1126/science.abe0298
Publication status	Published - 5 Feb 2021
Publication type	A1 Journal article-refereed

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Role of iodine oxoacids
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He, X.-C., Tham, Y. J., Dada, L., Wang, M., Finkenzeller, H., Stolzenburg, D., Iyer, S., Simon, M., Kürten, A., Shen, J., Rörup, B., Rissanen, M., Schobesberger, S., Baalbaki, R., Wang, D. S., Koenig, T. K., Jokinen, T., Sarnela, N., Beck, L. J., ... Sipilä, M. (2021). Role of iodine oxoacids in atmospheric aerosol nucleation. Science, 371(6529), 589-595. https://doi.org/10.1126/science.abe0298

@article{89f63544582643fdb7e5d26232b7a8aa,

title = "Role of iodine oxoacids in atmospheric aerosol nucleation",

abstract = "Iodic acid (HIO3) is known to form aerosol particles in coastal marine regions, but predicted nucleation and growth rates are lacking. Using the CERN CLOUD (Cosmics Leaving Outdoor Droplets) chamber, we find that the nucleation rates of HIO3 particles are rapid, even exceeding sulfuric acid–ammonia rates under similar conditions. We also find that ion-induced nucleation involves IO3− and the sequential addition of HIO3 and that it proceeds at the kinetic limit below +10°C. In contrast, neutral nucleation involves the repeated sequential addition of iodous acid (HIO2) followed by HIO3, showing that HIO2 plays a key stabilizing role. Freshly formed particles are composed almost entirely of HIO3, which drives rapid particle growth at the kinetic limit. Our measurements indicate that iodine oxoacid particle formation can compete with sulfuric acid in pristine regions of the atmosphere.",

author = "Xu-Cheng He and Tham, {Yee Jun} and Lubna Dada and Mingyi Wang and Henning Finkenzeller and Dominik Stolzenburg and Siddharth Iyer and Mario Simon and Andreas K{\"u}rten and Jiali Shen and Birte R{\"o}rup and Matti Rissanen and Siegfried Schobesberger and Rima Baalbaki and Wang, {Dongyu S.} and Koenig, {Theodore K.} and Tuija Jokinen and Nina Sarnela and Beck, {Lisa J.} and Jo{\~a}o Almeida and Stavros Amanatidis and Ant{\'o}nio Amorim and Farnoush Ataei and Andrea Baccarini and Barbara Bertozzi and Federico Bianchi and Sophia Brilke and Luc{\'i}a Caudillo and Dexian Chen and Randall Chiu and Biwu Chu and Ant{\'o}nio Dias and Aijun Ding and Josef Dommen and Jonathan Duplissy and Haddad, {Imad El} and Carracedo, {Lo{\"i}c Gonzalez} and Manuel Granzin and Armin Hansel and Martin Heinritzi and Victoria Hofbauer and Heikki Junninen and Juha Kangasluoma and Deniz Kemppainen and Changhyuk Kim and Weimeng Kong and Krechmer, {Jordan E.} and Aleksander Kvashin and Totti Laitinen and Houssni Lamkaddam and Lee, {Chuan Ping} and Katrianne Lehtipalo and Markus Leiminger and Zijun Li and Vladimir Makhmutov and Manninen, {Hanna E.} and Guillaume Marie and Ruby Marten and Serge Mathot and Mauldin, {Roy L.} and Bernhard Mentler and Ottmar M{\"o}hler and Tatjana M{\"u}ller and Wei Nie and Antti Onnela and Tuukka Pet{\"a}j{\"a} and Joschka Pfeifer and Maxim Philippov and Ananth Ranjithkumar and Alfonso Saiz-Lopez and Imre Salma and Wiebke Scholz and Simone Schuchmann and Benjamin Schulze and Gerhard Steiner and Yuri Stozhkov and Christian Tauber and Ant{\'o}nio Tom{\'e} and Thakur, {Roseline C.} and Olli V{\"a}is{\"a}nen and Miguel Vazquez-Pufleau and Wagner, {Andrea C.} and Yonghong Wang and Weber, {Stefan K.} and Winkler, {Paul M.} and Yusheng Wu and Mao Xiao and Chao Yan and Qing Ye and Arttu Ylisirni{\"o} and Marcel Zauner-Wieczorek and Qiaozhi Zha and Putian Zhou and Flagan, {Richard C.} and Joachim Curtius and Urs Baltensperger and Markku Kulmala and Veli-Matti Kerminen and Theo Kurt{\'e}n and Donahue, {Neil M.} and Rainer Volkamer and Jasper Kirkby and Worsnop, {Douglas R.} and Mikko Sipil{\"a}",

year = "2021",

month = feb,

day = "5",

doi = "10.1126/science.abe0298",

language = "English",

volume = "371",

pages = "589--595",

journal = "Science",

issn = "0036-8075",

publisher = "American Association for the Advancement of Science",

number = "6529",

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He, X-C, Tham, YJ, Dada, L, Wang, M, Finkenzeller, H, Stolzenburg, D, Iyer, S, Simon, M, Kürten, A, Shen, J, Rörup, B, Rissanen, M, Schobesberger, S, Baalbaki, R, Wang, DS, Koenig, TK, Jokinen, T, Sarnela, N, Beck, LJ, Almeida, J, Amanatidis, S, Amorim, A, Ataei, F, Baccarini, A, Bertozzi, B, Bianchi, F, Brilke, S, Caudillo, L, Chen, D, Chiu, R, Chu, B, Dias, A, Ding, A, Dommen, J, Duplissy, J, Haddad, IE, Carracedo, LG, Granzin, M, Hansel, A, Heinritzi, M, Hofbauer, V, Junninen, H, Kangasluoma, J, Kemppainen, D, Kim, C, Kong, W, Krechmer, JE, Kvashin, A, Laitinen, T, Lamkaddam, H, Lee, CP, Lehtipalo, K, Leiminger, M, Li, Z, Makhmutov, V, Manninen, HE, Marie, G, Marten, R, Mathot, S, Mauldin, RL, Mentler, B, Möhler, O, Müller, T, Nie, W, Onnela, A, Petäjä, T, Pfeifer, J, Philippov, M, Ranjithkumar, A, Saiz-Lopez, A, Salma, I, Scholz, W, Schuchmann, S, Schulze, B, Steiner, G, Stozhkov, Y, Tauber, C, Tomé, A, Thakur, RC, Väisänen, O, Vazquez-Pufleau, M, Wagner, AC, Wang, Y, Weber, SK, Winkler, PM, Wu, Y, Xiao, M, Yan, C, Ye, Q, Ylisirniö, A, Zauner-Wieczorek, M, Zha, Q, Zhou, P, Flagan, RC, Curtius, J, Baltensperger, U, Kulmala, M, Kerminen, V-M, Kurtén, T, Donahue, NM, Volkamer, R, Kirkby, J, Worsnop, DR & Sipilä, M 2021, 'Role of iodine oxoacids in atmospheric aerosol nucleation', Science, vol. 371, no. 6529, pp. 589-595. https://doi.org/10.1126/science.abe0298

TY - JOUR

T1 - Role of iodine oxoacids in atmospheric aerosol nucleation

AU - He, Xu-Cheng

AU - Tham, Yee Jun

AU - Dada, Lubna

AU - Wang, Mingyi

AU - Finkenzeller, Henning

AU - Stolzenburg, Dominik

AU - Iyer, Siddharth

AU - Simon, Mario

AU - Kürten, Andreas

AU - Shen, Jiali

AU - Rörup, Birte

AU - Rissanen, Matti

AU - Schobesberger, Siegfried

AU - Baalbaki, Rima

AU - Wang, Dongyu S.

AU - Koenig, Theodore K.

AU - Jokinen, Tuija

AU - Sarnela, Nina

AU - Beck, Lisa J.

AU - Almeida, João

AU - Amanatidis, Stavros

AU - Amorim, António

AU - Ataei, Farnoush

AU - Baccarini, Andrea

AU - Bertozzi, Barbara

AU - Bianchi, Federico

AU - Brilke, Sophia

AU - Caudillo, Lucía

AU - Chen, Dexian

AU - Chiu, Randall

AU - Chu, Biwu

AU - Dias, António

AU - Ding, Aijun

AU - Dommen, Josef

AU - Duplissy, Jonathan

AU - Haddad, Imad El

AU - Carracedo, Loïc Gonzalez

AU - Granzin, Manuel

AU - Hansel, Armin

AU - Heinritzi, Martin

AU - Hofbauer, Victoria

AU - Junninen, Heikki

AU - Kangasluoma, Juha

AU - Kemppainen, Deniz

AU - Kim, Changhyuk

AU - Kong, Weimeng

AU - Krechmer, Jordan E.

AU - Kvashin, Aleksander

AU - Laitinen, Totti

AU - Lamkaddam, Houssni

AU - Lee, Chuan Ping

AU - Lehtipalo, Katrianne

AU - Leiminger, Markus

AU - Li, Zijun

AU - Makhmutov, Vladimir

AU - Manninen, Hanna E.

AU - Marie, Guillaume

AU - Marten, Ruby

AU - Mathot, Serge

AU - Mauldin, Roy L.

AU - Mentler, Bernhard

AU - Möhler, Ottmar

AU - Müller, Tatjana

AU - Nie, Wei

AU - Onnela, Antti

AU - Petäjä, Tuukka

AU - Pfeifer, Joschka

AU - Philippov, Maxim

AU - Ranjithkumar, Ananth

AU - Saiz-Lopez, Alfonso

AU - Salma, Imre

AU - Scholz, Wiebke

AU - Schuchmann, Simone

AU - Schulze, Benjamin

AU - Steiner, Gerhard

AU - Stozhkov, Yuri

AU - Tauber, Christian

AU - Tomé, António

AU - Thakur, Roseline C.

AU - Väisänen, Olli

AU - Vazquez-Pufleau, Miguel

AU - Wagner, Andrea C.

AU - Wang, Yonghong

AU - Weber, Stefan K.

AU - Winkler, Paul M.

AU - Wu, Yusheng

AU - Xiao, Mao

AU - Yan, Chao

AU - Ye, Qing

AU - Ylisirniö, Arttu

AU - Zauner-Wieczorek, Marcel

AU - Zha, Qiaozhi

AU - Zhou, Putian

AU - Flagan, Richard C.

AU - Curtius, Joachim

AU - Baltensperger, Urs

AU - Kulmala, Markku

AU - Kerminen, Veli-Matti

AU - Kurtén, Theo

AU - Donahue, Neil M.

AU - Volkamer, Rainer

AU - Kirkby, Jasper

AU - Worsnop, Douglas R.

AU - Sipilä, Mikko

PY - 2021/2/5

Y1 - 2021/2/5

N2 - Iodic acid (HIO3) is known to form aerosol particles in coastal marine regions, but predicted nucleation and growth rates are lacking. Using the CERN CLOUD (Cosmics Leaving Outdoor Droplets) chamber, we find that the nucleation rates of HIO3 particles are rapid, even exceeding sulfuric acid–ammonia rates under similar conditions. We also find that ion-induced nucleation involves IO3− and the sequential addition of HIO3 and that it proceeds at the kinetic limit below +10°C. In contrast, neutral nucleation involves the repeated sequential addition of iodous acid (HIO2) followed by HIO3, showing that HIO2 plays a key stabilizing role. Freshly formed particles are composed almost entirely of HIO3, which drives rapid particle growth at the kinetic limit. Our measurements indicate that iodine oxoacid particle formation can compete with sulfuric acid in pristine regions of the atmosphere.

AB - Iodic acid (HIO3) is known to form aerosol particles in coastal marine regions, but predicted nucleation and growth rates are lacking. Using the CERN CLOUD (Cosmics Leaving Outdoor Droplets) chamber, we find that the nucleation rates of HIO3 particles are rapid, even exceeding sulfuric acid–ammonia rates under similar conditions. We also find that ion-induced nucleation involves IO3− and the sequential addition of HIO3 and that it proceeds at the kinetic limit below +10°C. In contrast, neutral nucleation involves the repeated sequential addition of iodous acid (HIO2) followed by HIO3, showing that HIO2 plays a key stabilizing role. Freshly formed particles are composed almost entirely of HIO3, which drives rapid particle growth at the kinetic limit. Our measurements indicate that iodine oxoacid particle formation can compete with sulfuric acid in pristine regions of the atmosphere.

U2 - 10.1126/science.abe0298

DO - 10.1126/science.abe0298

M3 - Article

SN - 0036-8075

VL - 371

SP - 589

EP - 595

JO - Science

JF - Science

IS - 6529

ER -

Role of iodine oxoacids in atmospheric aerosol nucleation

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