The dependence of tear behaviour on the microstructure of biaxially drawn polyester film

J. Kuusipalo, A.-M. Savijärvi, S. Norval, D. H. Mackerron

    Research output: Contribution to journalArticleScientificpeer-review

    12 Citations (Scopus)

    Abstract

    The structure-property relationship between a biaxially oriented film from poly(ethylene terephthalate) and its fracture behaviour measured using the Trouser Tear method, has been explored. X-ray diffraction (XRD) was used to characterise the orientation distribution of crystalline and non-crystalline material in the plane of the film and compared with the fracture energy, G(c) measured in four directions during tearing. The fracture energy averaged over the four directions ranged between 12 and 25 kJ m(-2), and was found to correlate closely to the draw ratio during manufacture and therefore the degree of molecular orientation. However the individual values of G(c) displayed a further level of complexity.

    The expected anisotropic character of the fracture energy was found to change systematically as a function of position across the original width of manufactured film. This feature compared well with the underlying, crystalline orientation distribution and provided strong evidence that under the mode III deformation of the tear test, the fracture mechanism involves the amorphous-crystallite surface boundary.

    Further support for this mechanism was provided by a simple model which, based on this assumption was shown to predict reliably, the anisotropic character of the film. (C) 2004 Kluwer Academic Publishers.

    Translated title of the contributionThe dependence of tear behaviours on the microstructure of biaxially drawn polyester film
    Original languageEnglish
    Pages (from-to)6909-6919
    Number of pages11
    JournalJournal of Materials Science
    Volume39
    Issue number23
    DOIs
    Publication statusPublished - 1 Dec 2004
    Publication typeA1 Journal article-refereed

    Keywords

    • STRETCHED POLY(ETHYLENE-TEREPHTHALATE) FILMS
    • MOLECULAR-ORIENTATION
    • PLASTIC FILMS
    • FRACTURE
    • MORPHOLOGY
    • POLYMERS
    • RUPTURE
    • RUBBER
    • WORK

    Publication forum classification

    • No publication forum level

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