YbPO4 crystals in as-drawn silica-based optical fibers

Zhuorui Lu; Natalia Vakula; Michèle Ude; Martiane Cabié; Thomas Neisius; François Orange; Franck Pigeonneau; Laeticia Petit; Wilfried Blanc

doi:10.1016/j.optmat.2023.113644

YbPO₄ crystals in as-drawn silica-based optical fibers

Zhuorui Lu
, Natalia Vakula
, Michèle Ude
, Martiane Cabié
, Thomas Neisius
, François Orange
, Franck Pigeonneau
, Laeticia Petit
, Wilfried Blanc^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › Scientific › peer-review

15 Citations (Scopus)

20 Downloads (Pure)

Abstract

MCVD germanosilica glass embedded with YbPO₄ crystals were for the first time drawn into optical fibers. Solution doping was used to embed the crystals in the silica soot prior to the collapsing step. We demonstrate, using scanning/transmission electron microscopes and confocal Raman microscope, that YbPO₄ crystals survive not only the MCVD process but also the drawing process despite the high temperature involved (up to 2100 °C) during fabrication processes. The fiber contains 100 nm-crystals with the same composition and structure as the as-prepared crystals. During the drawing process, these crystals tend to have a preferential orientation of their c-axis along the drawing direction. These results open a new route to fabricate glass-based composite fibers containing crystalline particles without additional post heat-treatment.

Original language	English
Article number	113644
Journal	Optical Materials
Volume	138
Early online date	4 Mar 2023
DOIs	https://doi.org/10.1016/j.optmat.2023.113644
Publication status	Published - 2023
Publication type	A1 Journal article-refereed

Funding

CCMA electron microscopy equipment was funded by Région Sud - Provence-Alpes-Côte d'Azur (France), the Conseil Départemental des Alpes-Maritimes (France), and the GIS-IBiSA (France). The Faculty of Engineering and Natural Sciences, Tampere University (Finland), is greatly acknowledged for the Doctoral Grant for NV. CCMA electron microscopy equipment was funded by Région Sud - Provence-Alpes-Côte d'Azur (France) , the Conseil Départemental des Alpes-Maritimes (France) , and the GIS-IBiSA (France) . The Faculty of Engineering and Natural Sciences, Tampere University (Finland) , is greatly acknowledged for the Doctoral Grant for NV.

Keywords

Chemical vapor deposition
Fiber
Scanning electron microscopy
Silica
Transmission electron microscopy

Publication forum classification

Publication forum level 1

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Atomic and Molecular Physics, and Optics
Spectroscopy
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Electrical and Electronic Engineering

Access to Document

10.1016/j.optmat.2023.113644

YbPO4 crystals in as-drawn silica-based optical fibersAccepted author manuscript, 999 KBLicence: CC BY-NC-ND

https://urn.fi/URN:NBN:fi:tuni-202307037038Licence: CC BY-NC-ND

Cite this

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title = "YbPO4 crystals in as-drawn silica-based optical fibers",

abstract = "MCVD germanosilica glass embedded with YbPO4 crystals were for the first time drawn into optical fibers. Solution doping was used to embed the crystals in the silica soot prior to the collapsing step. We demonstrate, using scanning/transmission electron microscopes and confocal Raman microscope, that YbPO4 crystals survive not only the MCVD process but also the drawing process despite the high temperature involved (up to 2100 °C) during fabrication processes. The fiber contains 100 nm-crystals with the same composition and structure as the as-prepared crystals. During the drawing process, these crystals tend to have a preferential orientation of their c-axis along the drawing direction. These results open a new route to fabricate glass-based composite fibers containing crystalline particles without additional post heat-treatment.",

keywords = "Chemical vapor deposition, Fiber, Scanning electron microscopy, Silica, Transmission electron microscopy",

author = "Zhuorui Lu and Natalia Vakula and Mich{\`e}le Ude and Martiane Cabi{\'e} and Thomas Neisius and Fran{\c c}ois Orange and Franck Pigeonneau and Laeticia Petit and Wilfried Blanc",

note = "Funding Information: CCMA electron microscopy equipment was funded by R{\'e}gion Sud - Provence-Alpes-C{\^o}te d'Azur (France), the Conseil D{\'e}partemental des Alpes-Maritimes (France), and the GIS-IBiSA (France). The Faculty of Engineering and Natural Sciences, Tampere University (Finland), is greatly acknowledged for the Doctoral Grant for NV. Funding Information: CCMA electron microscopy equipment was funded by R{\'e}gion Sud - Provence-Alpes-C{\^o}te d'Azur (France) , the Conseil D{\'e}partemental des Alpes-Maritimes (France) , and the GIS-IBiSA (France) . The Faculty of Engineering and Natural Sciences, Tampere University (Finland) , is greatly acknowledged for the Doctoral Grant for NV. Publisher Copyright: {\textcopyright} 2023",

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doi = "10.1016/j.optmat.2023.113644",

language = "English",

volume = "138",

journal = "Optical Materials",

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AU - Lu, Zhuorui

AU - Vakula, Natalia

AU - Ude, Michèle

AU - Cabié, Martiane

AU - Neisius, Thomas

AU - Orange, François

AU - Pigeonneau, Franck

AU - Petit, Laeticia

AU - Blanc, Wilfried

N1 - Funding Information: CCMA electron microscopy equipment was funded by Région Sud - Provence-Alpes-Côte d'Azur (France), the Conseil Départemental des Alpes-Maritimes (France), and the GIS-IBiSA (France). The Faculty of Engineering and Natural Sciences, Tampere University (Finland), is greatly acknowledged for the Doctoral Grant for NV. Funding Information: CCMA electron microscopy equipment was funded by Région Sud - Provence-Alpes-Côte d'Azur (France) , the Conseil Départemental des Alpes-Maritimes (France) , and the GIS-IBiSA (France) . The Faculty of Engineering and Natural Sciences, Tampere University (Finland) , is greatly acknowledged for the Doctoral Grant for NV. Publisher Copyright: © 2023

PY - 2023

Y1 - 2023

N2 - MCVD germanosilica glass embedded with YbPO4 crystals were for the first time drawn into optical fibers. Solution doping was used to embed the crystals in the silica soot prior to the collapsing step. We demonstrate, using scanning/transmission electron microscopes and confocal Raman microscope, that YbPO4 crystals survive not only the MCVD process but also the drawing process despite the high temperature involved (up to 2100 °C) during fabrication processes. The fiber contains 100 nm-crystals with the same composition and structure as the as-prepared crystals. During the drawing process, these crystals tend to have a preferential orientation of their c-axis along the drawing direction. These results open a new route to fabricate glass-based composite fibers containing crystalline particles without additional post heat-treatment.

AB - MCVD germanosilica glass embedded with YbPO4 crystals were for the first time drawn into optical fibers. Solution doping was used to embed the crystals in the silica soot prior to the collapsing step. We demonstrate, using scanning/transmission electron microscopes and confocal Raman microscope, that YbPO4 crystals survive not only the MCVD process but also the drawing process despite the high temperature involved (up to 2100 °C) during fabrication processes. The fiber contains 100 nm-crystals with the same composition and structure as the as-prepared crystals. During the drawing process, these crystals tend to have a preferential orientation of their c-axis along the drawing direction. These results open a new route to fabricate glass-based composite fibers containing crystalline particles without additional post heat-treatment.

KW - Chemical vapor deposition

KW - Fiber

KW - Scanning electron microscopy

KW - Silica

KW - Transmission electron microscopy

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DO - 10.1016/j.optmat.2023.113644

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