Abstrakti
Reduced density-matrix functional theory (RDMFT) has become an appealing alternative to density-functional theory to describe electronic properties of strongly correlated systems. Here we derive exact conditions for the suitability of RDMFT to describe the two-dimensional homogeneous electron gas, which is the base system for semiconductor quantum dots and quantum Hall devices, for example. Following the method of Cioslowski and Pernal [J. Chem. Phys. 111, 3396 (1999)] we focus on the properties of power functionals of the form f(n, n') = (nn')alpha for the scaling function in the exchange-correlation energy. We show that in order to have stable and analytic solutions, and for f to satisfy the homogeneous scaling constraint, the power is restricted to 1/4
| Alkuperäiskieli | Englanti |
|---|---|
| Artikkeli | 035104 |
| Sivumäärä | 6 |
| Julkaisu | Physical Review B |
| Vuosikerta | 84 |
| Numero | 3 |
| DOI - pysyväislinkit | |
| Tila | Julkaistu - 15 heinäk. 2011 |
| OKM-julkaisutyyppi | A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä |
Rahoitus
We thank Katarzyna Pernal, Klaas Giesbertz, Robert van Leeuwen, and Florian Eich for helpful comments and useful discussions. This work has been supported by the Academy of Finland.
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