Impact of Ag2O Content on the Optical and Spectroscopic Properties of Fluoro-Phosphate Glasses

Marwa Ennouri; Luukas Kuusela; Ifa Jlassi; Bernard Gelloz; Laeticia Petit; Habib Elhouichet

doi:10.3390/ma12213516

Impact of Ag2O Content on the Optical and Spectroscopic Properties of Fluoro-Phosphate Glasses

Marwa Ennouri, Luukas Kuusela, Ifa Jlassi, Bernard Gelloz, Laeticia Petit, Habib Elhouichet

Fysiikka

Tutkimustuotos: Artikkeli › Tieteellinen › vertaisarvioitu

10 Sitaatiot (Scopus)

17 Lataukset (Pure)

Abstrakti

Glasses with the system (84.60-x) NaPO3-5 ZnO-(9.40-x) NaF-x Ag2O-1 Er2O3, (x = 0, 2, 4, and 6) (mol%) were synthesized by the conventional melt-quenching method. The impact of the addition of Ag2O on the physical, thermal, structural, and optical properties of the glasses is discussed. The Judd-Oflet analysis was used to evaluate the radiative properties of the emission transitions of the glasses. The enhancement of luminescence properties due to Ag2O is discussed in terms of consequent changes in the local electromagnetic field, symmetry, and the ligand field around the Er3+ ion. The heat treatment of the glass was performed in order to precipitate Ag nanoparticles (NPs), which form as a layer at the surface of the heat-treated glasses as confirmed using scanning electron microscopy (SEM). The Ag NPs were found to increase the intensity of the emission at 1.5 µm.

Alkuperäiskieli	Englanti
Julkaisu	Materials
Vuosikerta	12
Numero	21
DOI - pysyväislinkit	https://doi.org/10.3390/ma12213516
Tila	Julkaistu - 26 lokak. 2019
OKM-julkaisutyyppi	A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä

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10.3390/ma12213516Lisenssi: CC BY

Impact of Ag2O Content on the Optical 2019Final published version, 3,57 MBLisenssi: CC BY

http://urn.fi/URN:NBN:fi:tuni-202003032488Lisenssi: CC BY

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@article{fa5046c6fb8240039d6bb4eb6ecc05c2,

title = "Impact of Ag2O Content on the Optical and Spectroscopic Properties of Fluoro-Phosphate Glasses",

abstract = "Glasses with the system (84.60-x) NaPO3-5 ZnO-(9.40-x) NaF-x Ag2O-1 Er2O3, (x = 0, 2, 4, and 6) (mol%) were synthesized by the conventional melt-quenching method. The impact of the addition of Ag2O on the physical, thermal, structural, and optical properties of the glasses is discussed. The Judd-Oflet analysis was used to evaluate the radiative properties of the emission transitions of the glasses. The enhancement of luminescence properties due to Ag2O is discussed in terms of consequent changes in the local electromagnetic field, symmetry, and the ligand field around the Er3+ ion. The heat treatment of the glass was performed in order to precipitate Ag nanoparticles (NPs), which form as a layer at the surface of the heat-treated glasses as confirmed using scanning electron microscopy (SEM). The Ag NPs were found to increase the intensity of the emission at 1.5 µm.",

author = "Marwa Ennouri and Luukas Kuusela and Ifa Jlassi and Bernard Gelloz and Laeticia Petit and Habib Elhouichet",

note = "INT=PHYS, {"}Kuusela, Luukas{"}",

year = "2019",

month = oct,

day = "26",

doi = "10.3390/ma12213516",

language = "English",

volume = "12",

journal = "Materials",

issn = "1996-1944",

publisher = "Multidisciplinary Digital Publishing Institute (MDPI)",

number = "21",

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TY - JOUR

T1 - Impact of Ag2O Content on the Optical and Spectroscopic Properties of Fluoro-Phosphate Glasses

AU - Ennouri, Marwa

AU - Kuusela, Luukas

AU - Jlassi, Ifa

AU - Gelloz, Bernard

AU - Petit, Laeticia

AU - Elhouichet, Habib

N1 - INT=PHYS, "Kuusela, Luukas"

PY - 2019/10/26

Y1 - 2019/10/26

N2 - Glasses with the system (84.60-x) NaPO3-5 ZnO-(9.40-x) NaF-x Ag2O-1 Er2O3, (x = 0, 2, 4, and 6) (mol%) were synthesized by the conventional melt-quenching method. The impact of the addition of Ag2O on the physical, thermal, structural, and optical properties of the glasses is discussed. The Judd-Oflet analysis was used to evaluate the radiative properties of the emission transitions of the glasses. The enhancement of luminescence properties due to Ag2O is discussed in terms of consequent changes in the local electromagnetic field, symmetry, and the ligand field around the Er3+ ion. The heat treatment of the glass was performed in order to precipitate Ag nanoparticles (NPs), which form as a layer at the surface of the heat-treated glasses as confirmed using scanning electron microscopy (SEM). The Ag NPs were found to increase the intensity of the emission at 1.5 µm.

AB - Glasses with the system (84.60-x) NaPO3-5 ZnO-(9.40-x) NaF-x Ag2O-1 Er2O3, (x = 0, 2, 4, and 6) (mol%) were synthesized by the conventional melt-quenching method. The impact of the addition of Ag2O on the physical, thermal, structural, and optical properties of the glasses is discussed. The Judd-Oflet analysis was used to evaluate the radiative properties of the emission transitions of the glasses. The enhancement of luminescence properties due to Ag2O is discussed in terms of consequent changes in the local electromagnetic field, symmetry, and the ligand field around the Er3+ ion. The heat treatment of the glass was performed in order to precipitate Ag nanoparticles (NPs), which form as a layer at the surface of the heat-treated glasses as confirmed using scanning electron microscopy (SEM). The Ag NPs were found to increase the intensity of the emission at 1.5 µm.

U2 - 10.3390/ma12213516

DO - 10.3390/ma12213516

M3 - Article

SN - 1996-1944

VL - 12

JO - Materials

JF - Materials

IS - 21

ER -

Impact of Ag2O Content on the Optical and Spectroscopic Properties of Fluoro-Phosphate Glasses

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