Iodine oxoacids enhance nucleation of sulfuric acid particles in the atmosphere

Xu Cheng He; Mario Simon; Siddharth Iyer; Hong Bin Xie; Birte Rörup; Jiali Shen; Henning Finkenzeller; Dominik Stolzenburg; Rongjie Zhang; Andrea Baccarini; Yee Jun Tham; Mingyi Wang; Stavros Amanatidis; Ana A. Piedehierro; Antonio Amorim; Rima Baalbaki; Zoé Brasseur; Lucía Caudillo; Biwu Chu; Lubna Dada; Jonathan Duplissy; Imad El Haddad; Richard C. Flagan; Manuel Granzin; Armin Hansel; Martin Heinritzi; Victoria Hofbauer; Tuija Jokinen; Deniz Kemppainen; Weimeng Kong; Jordan Krechmer; Andreas Kürten; Houssni Lamkaddam; Brandon Lopez; Fangfang Ma; Naser G.A. Mahfouz; Vladimir Makhmutov; Hanna E. Manninen; Guillaume Marie; Ruby Marten; Dario Massabò; Roy L. Mauldin; Bernhard Mentler; Antti Onnela; Tuukka Petäjä; Joschka Pfeifer; Maxim Philippov; Ananth Ranjithkumar; Matti P. Rissanen; Siegfried Schobesberger; Wiebke Scholz; Benjamin Schulze; Mihnea Surdu; Roseline C. Thakur; António Tomé; Andrea C. Wagner; Dongyu Wang; Yonghong Wang; Stefan K. Weber; André Welti; Paul M. Winkler; Marcel Zauner-Wieczorek; Urs Baltensperger; Joachim Curtius; Theo Kurtén; Douglas R. Worsnop; Rainer Volkamer; Katrianne Lehtipalo; Jasper Kirkby; Neil M. Donahue; Mikko Sipilä; Markku Kulmala

doi:10.1126/science.adh2526

Iodine oxoacids enhance nucleation of sulfuric acid particles in the atmosphere

Xu Cheng He, Mario Simon, Siddharth Iyer, Hong Bin Xie, Birte Rörup, Jiali Shen, Henning Finkenzeller, Dominik Stolzenburg, Rongjie Zhang, Andrea Baccarini, Yee Jun Tham, Mingyi Wang, Stavros Amanatidis, Ana A. Piedehierro, Antonio Amorim, Rima Baalbaki, Zoé Brasseur, Lucía Caudillo, Biwu Chu, Lubna DadaJonathan Duplissy, Imad El Haddad, Richard C. Flagan, Manuel Granzin, Armin Hansel, Martin Heinritzi, Victoria Hofbauer, Tuija Jokinen, Deniz Kemppainen, Weimeng Kong, Jordan Krechmer, Andreas Kürten, Houssni Lamkaddam, Brandon Lopez, Fangfang Ma, Naser G.A. Mahfouz, Vladimir Makhmutov, Hanna E. Manninen, Guillaume Marie, Ruby Marten, Dario Massabò, Roy L. Mauldin, Bernhard Mentler, Antti Onnela, Tuukka Petäjä, Joschka Pfeifer, Maxim Philippov, Ananth Ranjithkumar, Matti P. Rissanen, Siegfried Schobesberger, Wiebke Scholz, Benjamin Schulze, Mihnea Surdu, Roseline C. Thakur, António Tomé, Andrea C. Wagner, Dongyu Wang, Yonghong Wang, Stefan K. Weber, André Welti, Paul M. Winkler, Marcel Zauner-Wieczorek, Urs Baltensperger, Joachim Curtius, Theo Kurtén, Douglas R. Worsnop, Rainer Volkamer, Katrianne Lehtipalo, Jasper Kirkby, Neil M. Donahue, Mikko Sipilä, Markku Kulmala

Fysiikka

Tutkimustuotos: Artikkeli › Tieteellinen › vertaisarvioitu

23 Sitaatiot (Scopus)

12 Lataukset (Pure)

Abstrakti

The main nucleating vapor in the atmosphere is thought to be sulfuric acid (H2SO4), stabilized by ammonia (NH3). However, in marine and polar regions, NH3 is generally low, and H2SO4 is frequently found together with iodine oxoacids [HIOx, i.e., iodic acid (HIO3) and iodous acid (HIO2)]. In experiments performed with the CERN CLOUD (Cosmics Leaving OUtdoor Droplets) chamber, we investigated the interplay of H2SO4 and HIOx during atmospheric particle nucleation. We found that HIOx greatly enhances H2SO4(-NH3) nucleation through two different interactions. First, HIO3 strongly binds with H2SO4 in charged clusters so they drive particle nucleation synergistically. Second, HIO2 substitutes for NH3, forming strongly bound H2SO4-HIO2 acid-base pairs in molecular clusters. Global observations imply that HIOx is enhancing H2SO4(-NH3) nucleation rates 10- to 10,000-fold in marine and polar regions.

Alkuperäiskieli	Englanti
Sivut	1308-1314
Sivumäärä	7
Julkaisu	Science
Vuosikerta	382
Numero	6676
DOI - pysyväislinkit	https://doi.org/10.1126/science.adh2526
Tila	Julkaistu - 15 jouluk. 2023
OKM-julkaisutyyppi	A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä

Julkaisufoorumi-taso

Jufo-taso 3

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10.1126/science.adh2526

Iodine oxoacids enhance nucleation of sulfuric acid particles in the atmosphere
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Accepted author manuscript, 1,48 MBLisenssi: Unspecified

https://urn.fi/URN:NBN:fi:tuni-202401161519Lisenssi: Unspecified

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He, X. C., Simon, M., Iyer, S., Xie, H. B., Rörup, B., Shen, J., Finkenzeller, H., Stolzenburg, D., Zhang, R., Baccarini, A., Tham, Y. J., Wang, M., Amanatidis, S., Piedehierro, A. A., Amorim, A., Baalbaki, R., Brasseur, Z., Caudillo, L., Chu, B., ... Kulmala, M. (2023). Iodine oxoacids enhance nucleation of sulfuric acid particles in the atmosphere. Science, 382(6676), 1308-1314. https://doi.org/10.1126/science.adh2526

@article{13eab9046dbb4ca4b7f97bc898a596e7,

title = "Iodine oxoacids enhance nucleation of sulfuric acid particles in the atmosphere",

abstract = "The main nucleating vapor in the atmosphere is thought to be sulfuric acid (H2SO4), stabilized by ammonia (NH3). However, in marine and polar regions, NH3 is generally low, and H2SO4 is frequently found together with iodine oxoacids [HIOx, i.e., iodic acid (HIO3) and iodous acid (HIO2)]. In experiments performed with the CERN CLOUD (Cosmics Leaving OUtdoor Droplets) chamber, we investigated the interplay of H2SO4 and HIOx during atmospheric particle nucleation. We found that HIOx greatly enhances H2SO4(-NH3) nucleation through two different interactions. First, HIO3 strongly binds with H2SO4 in charged clusters so they drive particle nucleation synergistically. Second, HIO2 substitutes for NH3, forming strongly bound H2SO4-HIO2 acid-base pairs in molecular clusters. Global observations imply that HIOx is enhancing H2SO4(-NH3) nucleation rates 10- to 10,000-fold in marine and polar regions.",

author = "He, {Xu Cheng} and Mario Simon and Siddharth Iyer and Xie, {Hong Bin} and Birte R{\"o}rup and Jiali Shen and Henning Finkenzeller and Dominik Stolzenburg and Rongjie Zhang and Andrea Baccarini and Tham, {Yee Jun} and Mingyi Wang and Stavros Amanatidis and Piedehierro, {Ana A.} and Antonio Amorim and Rima Baalbaki and Zo{\'e} Brasseur and Luc{\'i}a Caudillo and Biwu Chu and Lubna Dada and Jonathan Duplissy and {El Haddad}, Imad and Flagan, {Richard C.} and Manuel Granzin and Armin Hansel and Martin Heinritzi and Victoria Hofbauer and Tuija Jokinen and Deniz Kemppainen and Weimeng Kong and Jordan Krechmer and Andreas K{\"u}rten and Houssni Lamkaddam and Brandon Lopez and Fangfang Ma and Mahfouz, {Naser G.A.} and Vladimir Makhmutov and Manninen, {Hanna E.} and Guillaume Marie and Ruby Marten and Dario Massab{\`o} and Mauldin, {Roy L.} and Bernhard Mentler and Antti Onnela and Tuukka Pet{\"a}j{\"a} and Joschka Pfeifer and Maxim Philippov and Ananth Ranjithkumar and Rissanen, {Matti P.} and Siegfried Schobesberger and Wiebke Scholz and Benjamin Schulze and Mihnea Surdu and Thakur, {Roseline C.} and Ant{\'o}nio Tom{\'e} and Wagner, {Andrea C.} and Dongyu Wang and Yonghong Wang and Weber, {Stefan K.} and Andr{\'e} Welti and Winkler, {Paul M.} and Marcel Zauner-Wieczorek and Urs Baltensperger and Joachim Curtius and Theo Kurt{\'e}n and Worsnop, {Douglas R.} and Rainer Volkamer and Katrianne Lehtipalo and Jasper Kirkby and Donahue, {Neil M.} and Mikko Sipil{\"a} and Markku Kulmala",

year = "2023",

month = dec,

day = "15",

doi = "10.1126/science.adh2526",

language = "English",

volume = "382",

pages = "1308--1314",

number = "6676",

}

He, XC, Simon, M, Iyer, S, Xie, HB, Rörup, B, Shen, J, Finkenzeller, H, Stolzenburg, D, Zhang, R, Baccarini, A, Tham, YJ, Wang, M, Amanatidis, S, Piedehierro, AA, Amorim, A, Baalbaki, R, Brasseur, Z, Caudillo, L, Chu, B, Dada, L, Duplissy, J, El Haddad, I, Flagan, RC, Granzin, M, Hansel, A, Heinritzi, M, Hofbauer, V, Jokinen, T, Kemppainen, D, Kong, W, Krechmer, J, Kürten, A, Lamkaddam, H, Lopez, B, Ma, F, Mahfouz, NGA, Makhmutov, V, Manninen, HE, Marie, G, Marten, R, Massabò, D, Mauldin, RL, Mentler, B, Onnela, A, Petäjä, T, Pfeifer, J, Philippov, M, Ranjithkumar, A, Rissanen, MP, Schobesberger, S, Scholz, W, Schulze, B, Surdu, M, Thakur, RC, Tomé, A, Wagner, AC, Wang, D, Wang, Y, Weber, SK, Welti, A, Winkler, PM, Zauner-Wieczorek, M, Baltensperger, U, Curtius, J, Kurtén, T, Worsnop, DR, Volkamer, R, Lehtipalo, K, Kirkby, J, Donahue, NM, Sipilä, M & Kulmala, M 2023, 'Iodine oxoacids enhance nucleation of sulfuric acid particles in the atmosphere', Science, Vuosikerta 382, Nro 6676, Sivut 1308-1314. https://doi.org/10.1126/science.adh2526

TY - JOUR

T1 - Iodine oxoacids enhance nucleation of sulfuric acid particles in the atmosphere

AU - He, Xu Cheng

AU - Simon, Mario

AU - Iyer, Siddharth

AU - Xie, Hong Bin

AU - Rörup, Birte

AU - Shen, Jiali

AU - Finkenzeller, Henning

AU - Stolzenburg, Dominik

AU - Zhang, Rongjie

AU - Baccarini, Andrea

AU - Tham, Yee Jun

AU - Wang, Mingyi

AU - Amanatidis, Stavros

AU - Piedehierro, Ana A.

AU - Amorim, Antonio

AU - Baalbaki, Rima

AU - Brasseur, Zoé

AU - Caudillo, Lucía

AU - Chu, Biwu

AU - Dada, Lubna

AU - Duplissy, Jonathan

AU - El Haddad, Imad

AU - Flagan, Richard C.

AU - Granzin, Manuel

AU - Hansel, Armin

AU - Heinritzi, Martin

AU - Hofbauer, Victoria

AU - Jokinen, Tuija

AU - Kemppainen, Deniz

AU - Kong, Weimeng

AU - Krechmer, Jordan

AU - Kürten, Andreas

AU - Lamkaddam, Houssni

AU - Lopez, Brandon

AU - Ma, Fangfang

AU - Mahfouz, Naser G.A.

AU - Makhmutov, Vladimir

AU - Manninen, Hanna E.

AU - Marie, Guillaume

AU - Marten, Ruby

AU - Massabò, Dario

AU - Mauldin, Roy L.

AU - Mentler, Bernhard

AU - Onnela, Antti

AU - Petäjä, Tuukka

AU - Pfeifer, Joschka

AU - Philippov, Maxim

AU - Ranjithkumar, Ananth

AU - Rissanen, Matti P.

AU - Schobesberger, Siegfried

AU - Scholz, Wiebke

AU - Schulze, Benjamin

AU - Surdu, Mihnea

AU - Thakur, Roseline C.

AU - Tomé, António

AU - Wagner, Andrea C.

AU - Wang, Dongyu

AU - Wang, Yonghong

AU - Weber, Stefan K.

AU - Welti, André

AU - Winkler, Paul M.

AU - Zauner-Wieczorek, Marcel

AU - Baltensperger, Urs

AU - Curtius, Joachim

AU - Kurtén, Theo

AU - Worsnop, Douglas R.

AU - Volkamer, Rainer

AU - Lehtipalo, Katrianne

AU - Kirkby, Jasper

AU - Donahue, Neil M.

AU - Sipilä, Mikko

AU - Kulmala, Markku

PY - 2023/12/15

Y1 - 2023/12/15

N2 - The main nucleating vapor in the atmosphere is thought to be sulfuric acid (H2SO4), stabilized by ammonia (NH3). However, in marine and polar regions, NH3 is generally low, and H2SO4 is frequently found together with iodine oxoacids [HIOx, i.e., iodic acid (HIO3) and iodous acid (HIO2)]. In experiments performed with the CERN CLOUD (Cosmics Leaving OUtdoor Droplets) chamber, we investigated the interplay of H2SO4 and HIOx during atmospheric particle nucleation. We found that HIOx greatly enhances H2SO4(-NH3) nucleation through two different interactions. First, HIO3 strongly binds with H2SO4 in charged clusters so they drive particle nucleation synergistically. Second, HIO2 substitutes for NH3, forming strongly bound H2SO4-HIO2 acid-base pairs in molecular clusters. Global observations imply that HIOx is enhancing H2SO4(-NH3) nucleation rates 10- to 10,000-fold in marine and polar regions.

AB - The main nucleating vapor in the atmosphere is thought to be sulfuric acid (H2SO4), stabilized by ammonia (NH3). However, in marine and polar regions, NH3 is generally low, and H2SO4 is frequently found together with iodine oxoacids [HIOx, i.e., iodic acid (HIO3) and iodous acid (HIO2)]. In experiments performed with the CERN CLOUD (Cosmics Leaving OUtdoor Droplets) chamber, we investigated the interplay of H2SO4 and HIOx during atmospheric particle nucleation. We found that HIOx greatly enhances H2SO4(-NH3) nucleation through two different interactions. First, HIO3 strongly binds with H2SO4 in charged clusters so they drive particle nucleation synergistically. Second, HIO2 substitutes for NH3, forming strongly bound H2SO4-HIO2 acid-base pairs in molecular clusters. Global observations imply that HIOx is enhancing H2SO4(-NH3) nucleation rates 10- to 10,000-fold in marine and polar regions.

U2 - 10.1126/science.adh2526

DO - 10.1126/science.adh2526

M3 - Article

C2 - 38096284

AN - SCOPUS:85179768022

SN - 1095-9203

VL - 382

SP - 1308

EP - 1314

JO - Science

JF - Science

IS - 6676

ER -

Iodine oxoacids enhance nucleation of sulfuric acid particles in the atmosphere

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